Photomechanical Actuation of Ligand Geometry in Enantioselective Catalysis

2014 ◽  
Vol 53 (52) ◽  
pp. 14508-14511 ◽  
Author(s):  
Zachary S. Kean ◽  
Sergey Akbulatov ◽  
Yancong Tian ◽  
Ross A. Widenhoefer ◽  
Roman Boulatov ◽  
...  
Keyword(s):  
Enantioselective Catalysis ◽  
Photomechanical Actuation

Photomechanical Actuation of Ligand Geometry in Enantioselective Catalysis

2014 ◽  
Vol 126 (52) ◽  
pp. 14736-14739 ◽  
Author(s):  
Zachary S. Kean ◽  
Sergey Akbulatov ◽  
Yancong Tian ◽  
Ross A. Widenhoefer ◽  
Roman Boulatov ◽  
...  
Keyword(s):  
Enantioselective Catalysis ◽  
Photomechanical Actuation

Heterogeneous Enantioselective Catalysis with Chiral Encoded Mesoporous Pt−Ir Films Supported on Ni Foam

2021 ◽  
Author(s):  
Sunpet Assavapanumat ◽  
Sopon Butcha ◽  
Somlak Ittisanronnachai ◽  
Alexander Kuhn ◽  
Chularat Wattanakit
Keyword(s):  
Enantioselective Catalysis ◽  
Ni Foam

Calcium catalyzed enantioselective intramolecular alkene hydroamination with chiral C2-symmetric bis-amide ligands

2021 ◽  
Vol 50 (9) ◽  
pp. 3178-3185 ◽  
Author(s):  
Philipp C. Stegner ◽  
Jonathan Eyselein ◽  
Gerd M. Ballmann ◽  
Jens Langer ◽  
Jochen Schmidt ◽  
...  
Keyword(s):  
Enantioselective Catalysis ◽  
Amide Ligands ◽  
Calcium Catalysts

Enantioselective catalysis with calcium catalysts is challenging due to facile loss of the chiral spectator ligand. Herein a series of bis-amide calcium catalysts with chiral binaphtalene bridges is introduced.

Asymmetrische Katalysen, 25 [1]. C5H5Mn(CO)2-Komplexe von optisch aktiven Chelatphosphanen als einzähnige Liganden in der enantioselektiven Katalyse / Asymmetric Catalyses, 25 [1]. C5H5Mn(CO)2 Complexes of Optically Active Chelate Phosphanes as Monodentate Ligands in Enantioselective Catalysis

1985 ◽  
Vol 40 (10) ◽  
pp. 1243-1249 ◽  
Author(s):  
Henri Brunner ◽  
Alfons Knott
Keyword(s):  
Cinnamic Acid ◽  
Enantioselective Hydrogenation ◽  
Optically Active ◽  
Enantioselective Catalysis ◽  
Dinuclear Complexes ◽  
Bidentate Ligands ◽  
Monodentate Ligand ◽  
Mononuclear Complexes ◽  
Monodentate Ligands

The chelate phosphanes Diphos, Diop, and Norphos were reacted with C5H5Mn(CO)2THF and CH3C5H4Mn(CO)2THF to give mononuclear complexes, containing the phosphanes as unidentate or as bidentate ligands, and dinuclear complexes, containing bridging phosphane ligands. In C5H5Mn(CO)2Diop one of the two P(C6H5)2 groups of Diop is coordinated to the C5H5Mn(CO)2 fragment; the uncoordinated P(C6H5)2 group makes it a monodentate ligand. C5H5Mn(CO)2Diop together with [Rh(cod)Cl]2 was used as an in situ catalyst in the enantioselective hydrogenation of (Z)-a-[N -acetam ino]cinnamic acid (78.4% ee) and in the enantioselective hydrosilylation of acetophenone with diphenylsilane (6.7% ee).

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