Highly Efficient “On Water” Catalyst-Free Nucleophilic Addition Reactions Using Difluoroenoxysilanes: Dramatic Fluorine Effects

2014 ◽  
Vol 53 (36) ◽  
pp. 9512-9516 ◽  
Author(s):  
Jin-Sheng Yu ◽  
Yun-Lin Liu ◽  
Jing Tang ◽  
Xin Wang ◽  
Jian Zhou
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Catalyst Free ◽  
Highly Efficient

Highly Efficient “On Water” Catalyst-Free Nucleophilic Addition Reactions Using Difluoroenoxysilanes: Dramatic Fluorine Effects

2014 ◽  
Vol 126 (36) ◽  
pp. 9666-9670 ◽  
Author(s):  
Jin-Sheng Yu ◽  
Yun-Lin Liu ◽  
Jing Tang ◽  
Xin Wang ◽  
Jian Zhou
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Catalyst Free ◽  
Highly Efficient

Catalyst-free nucleophilic addition reactions of silyl glyoxylates in water

2018 ◽  
Vol 20 (6) ◽  
pp. 1228-1232 ◽  
Author(s):  
Man-Yi Han ◽  
Jing Lin ◽  
Wei Li ◽  
Wen-Yu Luan ◽  
Pei-Lin Mai ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reaction ◽  
Addition Reactions ◽  
Catalyst Free ◽  
Silyl Glyoxylates ◽  
Efficient Route ◽  
Novel Catalyst

A novel catalyst-free addition reaction of thiols to silyl glyoxylates is developed in water, providing an efficient route for the synthesis of α-hydroxysilanes.

The first peripherally masked thiol dendrimers: a facile and highly efficient functionalization strategy of polyester dendrimers via one-pot xanthate deprotection/thiol–acrylate Michael addition reactions

2014 ◽  
Vol 50 (50) ◽  
pp. 6574-6577 ◽  
Author(s):  
Sam E. R. Auty ◽  
Oliver Andrén ◽  
Michael Malkoch ◽  
Steven P. Rannard
Keyword(s):  
Michael Addition ◽  
Addition Reactions ◽  
One Pot ◽  
Highly Efficient

We present the first xanthate surface functional dendrimers which undergo rapid one-pot deprotection to thiols and subsequent acrylate Michael addition .

scholarly journals Nucleophilic Addition Reactions of Nitriles to Nitrones under Mild Silylation Conditions

Synlett ◽  
2014 ◽  
Vol 25 (13) ◽  
pp. 1863-1868 ◽  
Author(s):  
Fumihiko Yoshimura ◽  
Keiji Tanino ◽  
Taiki Abe
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions

Amide-Directed Reactions of Small Carbocycles

2021 ◽  
Vol 25 ◽  
Author(s):  
Pavel M. Yamanushkin ◽  
Marina Rubina ◽  
Michael Rubin
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

: The topic of this review is the amide-directed functionalization of strained carbocycles — specifically, unsaturated or saturated three- and four-membered rings. The following approaches are discussed: a) directed carbometallation and hydrometallation of cyclopropenes catalyzed by transition metals; b) directed metal-templated nucleophilic addition reactions; c) directed C-H functionalization, including transition metal-catalyzed C-H-activation reactions; and d) directed radical additions.

Highly efficient and catalyst-free synthesis of substituted thioureas in water

2011 ◽  
Vol 15 (3) ◽  
pp. 809-815 ◽  
Author(s):  
Shi-Feng Gan ◽  
Jie-Ping Wan ◽  
Yuan-Jiang Pan ◽  
Cui-Rong Sun
Keyword(s):  
Catalyst Free ◽  
Highly Efficient
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