Carbon Dioxide Sensitivity of Zeolitic Imidazolate Frameworks

2014 ◽  
Vol 53 (29) ◽  
pp. 7471-7474 ◽  
Author(s):  
Cristina Mottillo ◽  
Tomislav Friščić
2014 ◽  
Vol 126 (29) ◽  
pp. 7601-7604 ◽  
Author(s):  
Cristina Mottillo ◽  
Tomislav Friščić

2014 ◽  
Vol 126 (40) ◽  
pp. 10821-10824 ◽  
Author(s):  
Nhung T. T. Nguyen ◽  
Hiroyasu Furukawa ◽  
Felipe Gándara ◽  
Hoang T. Nguyen ◽  
Kyle E. Cordova ◽  
...  

MRS Bulletin ◽  
2009 ◽  
Vol 34 (9) ◽  
pp. 682-690 ◽  
Author(s):  
Omar M. Yaghi ◽  
Qiaowei Li

AbstractReticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.


Thorax ◽  
2010 ◽  
Vol 65 (Suppl 4) ◽  
pp. A134-A134
Author(s):  
K. A. Bazin ◽  
S. Moosavi ◽  
K. Murphy ◽  
A. Perkins ◽  
M. Hickson ◽  
...  

2019 ◽  
Vol 19 (6) ◽  
pp. 3059-3078 ◽  
Author(s):  
Xinbo Lian ◽  
Leilei Xu ◽  
Mindong Chen ◽  
Cai-e Wu ◽  
Wenjing Li ◽  
...  

The carbon dioxide (CO2) is notorious as the greenhouse gas, which could cause the global warming and climate change. Therefore, the reduction of the atmospheric CO2 emissions from power plants and other industrial facilities has become as an increasingly urgent concern. In the recent years, CO2 capture and storage technologies have received a worldwide attention. Adsorption is considered as one of the efficient options for CO2 capture because of its cost advantage, low energy requirement and extensive applicability over a relatively wide range of temperature and pressure. The metal organic frameworks (MOFs) show widely potential application prospects in CO2 capture and storage owing to their outstanding textural properties, such as the extraordinarily high specific surface area, tunable pore size, ultrahigh porosity (up to 90%), high crystallinity, adjustable internal surface properties, and controllable structure. Herein, the most important research progress of MOFs materials on the CO2 capture and storage in recent years has been comprehensively reviewed. The extraordinary characteristics and CO2 capture performance of Zeolitic Imidazolate Frameworks (ZIFs), Bio-metal organic frameworks (bio-MOFs), IL@MOFs and MOF-composite materials were highlighted. The promising strategies for improving the CO2 adsorption properties of MOFs materials, especially the low-pressure adsorption performance under actual flue gas conditions, are also carefully summarized. Besides, CO2 is considered as an abundant, nontoxic, nonflammable, and renewable C1 resource for the synthesis of useful chemicals and fuels. The potential routes for resource utilization of the captured CO2 are briefly proposed.


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