Surfactant-Free Nonaqueous Synthesis of Plasmonic Molybdenum Oxide Nanosheets with Enhanced Catalytic Activity for Hydrogen Generation from Ammonia Borane under Visible Light

2014 ◽  
Vol 53 (11) ◽  
pp. 2910-2914 ◽  
Author(s):  
Hefeng Cheng ◽  
Takashi Kamegawa ◽  
Kohsuke Mori ◽  
Hiromi Yamashita
2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.


RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105940-105947 ◽  
Author(s):  
Daohua Sun ◽  
Pengyao Li ◽  
Bin Yang ◽  
Yan Xu ◽  
Jiale Huang ◽  
...  

Monodisperse AgPd alloy NPs showed remarkable catalytic activity towards the generation of hydrogen from the methanolysis of ammonia borane at room temperature.


2017 ◽  
Vol 5 (46) ◽  
pp. 24116-24125 ◽  
Author(s):  
Jianmin Chen ◽  
Junying Chen ◽  
Yingwei Li

A novel approach, combining sulfurization and cation-exchange processes, is developed to fabricate hollow ZnCdS rhombic dodecahedral cages from ZIF-8, which exhibit superior catalytic activity and durability for hydrogen evolution from water splitting under cocatalyst-free and visible-light driven conditions.


2016 ◽  
Vol 852 ◽  
pp. 252-256
Author(s):  
Wei Dong Qi ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Yong Jin Zou ◽  
Hai Liang Chu

Ammonia borane received extensive attention due to its hydrogen content as high as 19.6%. In present article we prepared the Pt-Co/C catalyst via ultrasonic immersion method and in situ reduction method. The catalyst was characterized by measuring the specific area. The influence of the catalyst on the properties of the hydrolysis of ammonia borane was tested, and the catalytic activity of the catalyst in cycle use was verified. Results shows that the catalytic activity of Pt0.5Co0.5/C is the highest, and the maximum hydrogen generation rate is 7229.613 mL/ (g ·min). It was verified that it remained good catalytic activity after cycle use for more than 10 times.


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