Mechanism of the Asymmetric Hydrogenation of Exocyclic α,β-Unsaturated Carbonyl Compounds with an Iridium/BiphPhox Catalyst: NMR and DFT Studies

2014 ◽  
Vol 53 (7) ◽  
pp. 1901-1905 ◽  
Author(s):  
Yuanyuan Liu ◽  
Ilya D. Gridnev ◽  
Wanbin Zhang
Keyword(s):  
Carbonyl Compounds ◽  
Asymmetric Hydrogenation ◽  
Dft Studies

Rhodium-catalyzed asymmetric hydrogenation of exocyclic α,β-unsaturated carbonyl compounds

2020 ◽  
Vol 18 (5) ◽  
pp. 856-859 ◽  
Author(s):  
Jiaxin Yang ◽  
Xiuxiu Li ◽  
Cai You ◽  
Shuailong Li ◽  
Yu-Qing Guan ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Asymmetric Hydrogenation ◽  
Efficient Approach

A general and efficient approach for the synthesis of α-chiral cyclic lactones, lactams and ketones has been developed via Rh-catalyzed asymmetric hydrogenation.

ChemInform Abstract: SpinPhox/Iridium(I)-Catalyzed Asymmetric Hydrogenation of Cyclic α-Alkylidene Carbonyl Compounds.

ChemInform ◽  
2014 ◽  
Vol 45 (32) ◽  
pp. no-no
Author(s):  
Xu Liu ◽  
Zhaobin Han ◽  
Zheng Wang ◽  
Kuiling Ding
Keyword(s):  
Carbonyl Compounds ◽  
Asymmetric Hydrogenation

Chemoselective asymmetric hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols catalysed by [Ir(binap)(cod)]BF4-aminophosphine

1992 ◽  
Vol 428 (1-2) ◽  
pp. 213-222 ◽  
Author(s):  
Kazushi Mashima ◽  
Takeshi Akutagawa ◽  
Xiaoyong Zhang ◽  
Hidemasa Takaya ◽  
Takanao Taketomi ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Asymmetric Hydrogenation ◽  
Allylic Alcohols

SpinPhox/Iridium(I)-Catalyzed Asymmetric Hydrogenation of Cyclic α-Alkylidene Carbonyl Compounds

2014 ◽  
Vol 126 (7) ◽  
pp. 2009-2013 ◽  
Author(s):  
Xu Liu ◽  
Zhaobin Han ◽  
Zheng Wang ◽  
Kuiling Ding
Keyword(s):  
Carbonyl Compounds ◽  
Asymmetric Hydrogenation
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