An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

2013 ◽  
Vol 52 (49) ◽  
pp. 12883-12887 ◽  
Author(s):  
Adrien Quintard ◽  
Thierry Constantieux ◽  
Jean Rodriguez
Keyword(s):  
Allylic Alcohols ◽  
Cascade Process

scholarly journals Front Cover Picture: Chemo-Enzymatic Oxidative Rearrangement of Tertiary Allylic Alcohols: Synthetic Application and Integration into a Cascade Process (Adv. Synth. Catal. 19/2018)

2018 ◽  
Vol 360 (19) ◽  
pp. 3613-3613
Author(s):  
Elisabetta Brenna ◽  
Michele Crotti ◽  
Matteo De Pieri ◽  
Francesco G. Gatti ◽  
Gabriele Manenti ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Cascade Process ◽  
Front Cover ◽  
Oxidative Rearrangement ◽  
Synthetic Application

ChemInform Abstract: An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols.

ChemInform ◽  
2014 ◽  
Vol 45 (19) ◽  
pp. no-no
Author(s):  
Adrien Quintard ◽  
Thierry Constantieux ◽  
Jean Rodriguez
Keyword(s):  
Allylic Alcohols ◽  
Cascade Process

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

2013 ◽  
Vol 125 (49) ◽  
pp. 13121-13125 ◽  
Author(s):  
Adrien Quintard ◽  
Thierry Constantieux ◽  
Jean Rodriguez
Keyword(s):  
Allylic Alcohols ◽  
Cascade Process

scholarly journals Chemo-Enzymatic Oxidative Rearrangement of Tertiary Allylic Alcohols: Synthetic Application and Integration into a Cascade Process

2018 ◽  
Vol 360 (19) ◽  
pp. 3677-3686 ◽  
Author(s):  
Elisabetta Brenna ◽  
Michele Crotti ◽  
Matteo De Pieri ◽  
Francesco G. Gatti ◽  
Gabriele Manenti ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Cascade Process ◽  
Oxidative Rearrangement ◽  
Synthetic Application

Active MnO2 As a Mild Oxidizing Reagent for the Controlled Oxidation of Benzylic and Allylic Alcohols

2012 ◽  
Vol 2 (6) ◽  
pp. 48-48
Author(s):  
Y. M. Nandurkar Y. M. Nandurkar ◽  
◽  
B. B. Bahule B. B. Bahule
Keyword(s):  
Allylic Alcohols

Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols

2019 ◽  
Author(s):  
Ke-Yin Ye ◽  
Terry McCallum ◽  
Song Lin
Keyword(s):  
Ring Opening ◽  
High Reactivity ◽  
Hydrogen Atom Transfer ◽  
Organic Radicals ◽  
Epoxide Ring ◽  
Allylic Alcohols ◽  
Epoxide Ring Opening ◽  
Bond Forming ◽  
Co Catalysts ◽  
The Rich

Organic radicals are generally short-lived intermediates with exceptionally high reactivity. Strategically, achieving synthetically useful transformations mediated by organic radicals requires both efficient initiation and selective termination events. Here, we report a new catalytic strategy, namely bimetallic radical redox-relay, in the regio- and stereoselective rearrangement of epoxides to allylic alcohols. This approach exploits the rich redox chemistry of Ti and Co complexes and merges reductive epoxide ring opening (initiation) with hydrogen atom transfer (termination). Critically, upon effecting key bond-forming and -breaking events, Ti and Co catalysts undergo proton-transfer/electron-transfer with one another to achieve turnover, thus constituting a truly synergistic dual catalytic system.<br>

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed

scholarly journals Synthesis of Fused Dihydroazepine Derivatives of Fullerenes by a Rh‐Catalyzed Cascade Process

2021 ◽  
Author(s):  
Albert Artigas ◽  
Cristina Castanyer ◽  
Nil Roig ◽  
Agustí Lledó ◽  
Miquel Solà ◽  
...  
Keyword(s):  
Cascade Process ◽  
Derivatives Of
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