Why is Gold such a Good Catalyst for Oxygen Reduction in Alkaline Media?

2012 ◽  
Vol 51 (52) ◽  
pp. 12997-13000 ◽  
Author(s):  
P. Quaino ◽  
N. B. Luque ◽  
R. Nazmutdinov ◽  
E. Santos ◽  
Wolfgang Schmickler
Keyword(s):  
Oxygen Reduction ◽  
Alkaline Media ◽  
Good Catalyst

Epitaxial Thin-Film Spinel Oxides as Oxygen Reduction Electrocatalysts in Alkaline Media

2021 ◽  
Author(s):  
Yao Yang ◽  
Rui Zeng ◽  
Hanjong Paik ◽  
Ding-Yuan Kuo ◽  
Darrell G. Schlom ◽  
...  
Keyword(s):  
Thin Film ◽  
Oxygen Reduction ◽  
Alkaline Media ◽  
Epitaxial Thin Film ◽  
Spinel Oxides

scholarly journals Superior FexN electrocatalyst derived from 1,1′-diacetylferrocene for oxygen reduction reaction in alkaline and acidic media

2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Current Density ◽  
Active Sites ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Acidic Media ◽  
Onset Potential ◽  
Acidic And Alkaline Media ◽  
The Stability

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.

Electrochemical and spectroscopic study of novel Cu and Fe-based catalysts for oxygen reduction in alkaline media

2012 ◽  
Vol 213 ◽  
pp. 169-179 ◽  
Author(s):  
Qinggang He ◽  
Xiaofang Yang ◽  
Ruihua He ◽  
Agustín Bueno-López ◽  
Hamish Miller ◽  
...  
Keyword(s):  
Spectroscopic Study ◽  
Oxygen Reduction ◽  
Alkaline Media

Mesoporous TiN as a Noncarbon Support of Ag-Rich PtAg Nanoalloy Catalysts for Oxygen Reduction Reaction in Alkaline Media

ChemSusChem ◽  
2014 ◽  
Vol 7 (12) ◽  
pp. 3356-3361 ◽  
Author(s):  
Zhiming Cui ◽  
Minghui Yang ◽  
Hao Chen ◽  
Mengtian Zhao ◽  
Francis J. DiSalvo
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Alkaline Media

Hybrid palladium-ceria nanorod electrocatalysts applications in oxygen reduction and ethanol oxidation reactions in alkaline media

2021 ◽  
Author(s):  
Victor S. Pinheiro ◽  
Felipe M. Souza ◽  
Tuani C. Gentil ◽  
Luanna S. Parreira ◽  
Bruno L. Batista ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Ethanol Oxidation ◽  
Alkaline Media ◽  
Oxidation Reactions

High Active Hollow Nitrogen-Doped Carbon Microspheres for Oxygen Reduction in Alkaline Media

Fuel Cells ◽  
2012 ◽  
Vol 12 (3) ◽  
pp. 506-510 ◽  
Author(s):  
Y. M. Yu ◽  
J. H. Zhang ◽  
C. H. Xiao ◽  
J. D. Zhong ◽  
X. H. Zhang ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Alkaline Media ◽  
Carbon Microspheres ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

Fe–N–C Electrocatalysts in the Oxygen and Nitrogen Cycles in Alkaline Media: The Role of Iron Carbide

2021 ◽  
Author(s):  
Tomer Y. Burshtein ◽  
Denial Aias ◽  
Jin Wang ◽  
Matan Sananis ◽  
Eliyahu M. Farber ◽  
...  
Keyword(s):  
Free Energy ◽  
Energy Conversion ◽  
Oxygen Reduction ◽  
Iron Carbide ◽  
Alkaline Media ◽  
Great Promise ◽  
Nitrogen Cycles

Fe–N–C electrocatalysts hold a great promise for Pt-free energy conversion, driving the electrocatalysis of oxygen reduction and evolution, oxidation of nitrogen fuels, and reduction of N2, CO2, and NOx. Nevertheless,...

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