High-Molecular-Weight Poly(vinylphosphonate)s by Single-Component Living Polymerization Initiated by Rare-Earth-Metal Complexes

2010 ◽  
Vol 49 (20) ◽  
pp. 3489-3491 ◽  
Author(s):  
Uwe B. Seemann ◽  
Joachim E. Dengler ◽  
Bernhard Rieger
Keyword(s):  
Molecular Weight ◽  
Rare Earth ◽  
Metal Complexes ◽  
High Molecular Weight ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Living Polymerization ◽  
Single Component ◽  
Rare Earth Metal Complexes ◽  
High Molecular Weight Poly

Bis(phenolate) N-heterocyclic carbene rare earth metal complexes: synthesis, characterization and applications in the polymerization of n-hexyl isocyanate

RSC Advances ◽  
2015 ◽  
Vol 5 (101) ◽  
pp. 83295-83303 ◽  
Author(s):  
Min Zhang ◽  
Jingjing Zhang ◽  
Xufeng Ni ◽  
Zhiquan Shen
Keyword(s):  
Molecular Weight ◽  
Rare Earth ◽  
Metal Complexes ◽  
High Molecular Weight ◽  
Molecular Weight Distribution ◽  
Rare Earth Metal ◽  
Weight Distribution ◽  
Earth Metal ◽  
Narrow Molecular Weight Distribution ◽  
Rare Earth Metal Complexes

Polyhexyl isocyanantes catalyzed by N-heterocyclic carbene rare earth metal complexes show high molecular weight with narrow molecular weight distribution.

Highly syndioselective coordination (co)polymerization of vinyl heteroaromatic monomers using rare-earth-metal complexes

2020 ◽  
Vol 11 (48) ◽  
pp. 7650-7655
Author(s):  
Tiantian Wang ◽  
Chunji Wu ◽  
Dongmei Cui
Keyword(s):  
Molecular Weight ◽  
Rare Earth ◽  
Metal Complexes ◽  
High Activity ◽  
High Molecular Weight ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Coordination Polymerization ◽  
Metal Precursors ◽  
Rare Earth Metal Complexes

This paper demonstrates the coordination polymerization of vinylbenzothiophene and its copolymerization with styrene with high activity and perfect syndioselectivity to give high molecular weight products by using rare-earth-metal precursors.

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