Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence

2010 ◽  
Vol 49 (6) ◽  
pp. 1139-1142 ◽  
Author(s):  
Zhenhua Zhang ◽  
Yiyang Liu ◽  
Mingxing Gong ◽  
Xiaokun Zhao ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Insertion Sequence ◽  
Migratory Insertion ◽  
Palladium Catalyzed

Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence

2010 ◽  
Vol 122 (6) ◽  
pp. 1157-1160 ◽  
Author(s):  
Zhenhua Zhang ◽  
Yiyang Liu ◽  
Mingxing Gong ◽  
Xiaokun Zhao ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Insertion Sequence ◽  
Migratory Insertion ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence.

ChemInform ◽  
2010 ◽  
Vol 41 (21) ◽  
pp. no-no
Author(s):  
Zhenhua Zhang ◽  
Yiyang Liu ◽  
Mingxing Gong ◽  
Xiaokun Zhao ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Insertion Sequence ◽  
Migratory Insertion ◽  
Palladium Catalyzed

scholarly journals Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination

2021 ◽  
Author(s):  
Kedong Yuan ◽  
Taisiia Feoktistova ◽  
Paul Ha-Yeon Cheong ◽  
Ryan A. Altman
Keyword(s):  
Catalytic System ◽  
Insertion Sequence ◽  
Radical Arylation ◽  
Migratory Insertion

PdII/CuI co-catalyze a desulfitative arylation of aliphatic gem-difluoroalkenes in a radical arylation/migratory insertion sequence that avoids β-F elimination.

scholarly journals Recent Advances in Palladium-Catalyzed Bridging C–H Activation by Using Alkenes, Alkynes or Diazo Compounds as Bridging Reagents

Synthesis ◽  
2020 ◽  
Vol 53 (02) ◽  
pp. 238-254
Author(s):  
Fulin Zhang ◽  
Luoting Xin ◽  
Saihu Liao ◽  
Xueliang Huang ◽  
Yinghua Yu
Keyword(s):  
Bond Distance ◽  
Short Review ◽  
Diazo Compounds ◽  
Bond Functionalization ◽  
Migratory Insertion ◽  
Intramolecular Reactions ◽  
Palladium Catalyzed ◽  
Direct Functionalization ◽  
Intermolecular Reactions ◽  
Metal Catalyzed

AbstractTransition-metal-catalyzed direct inert C–H bond functionalization has attracted much attention over the past decades. However, because of the high strain energy of the suspected palladacycle generated via C–H bond palladation, direct functionalization of a C–H bond less than a three-bond distance from a catalyst center is highly challenging. In this short review, we summarize the advances on palladium-catalyzed bridging C–H activation, in which an inert proximal C–H bond palladation is promoted by the elementary step of migratory insertion of an alkene, an alkyne or a metal carbene intermediate.1 Introduction2 Palladium-Catalyzed Alkene Bridging C–H Activation2.1 Intramolecular Reactions2.2 Intermolecular Reactions3 Palladium-Catalyzed Alkyne Bridging C–H Activation3.1 Intermolecular Reactions3.2 Intramolecular Reactions4 Palladium-Catalyzed Carbene Bridging C–H Activation5 Conclusion and Outlook

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

2018 ◽  
Vol 54 (92) ◽  
pp. 12994-12997 ◽  
Author(s):  
Qiu-Chao Mu ◽  
Xing-Ben Wang ◽  
Fei Ye ◽  
Yu-Li Sun ◽  
Xing-Feng Bai ◽  
...  
Keyword(s):  
Alkyl Halides ◽  
One Pot ◽  
Migratory Insertion ◽  
Palladium Catalyzed ◽  
Vinyl Silanes

One-pot formation of (E)-vinyl silanes and (E)-silyl-substituted α, β-unsaturated amides could be completed easily via palladium carbene migratory insertion in good yields and high chemoselectivity.

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