Growth of Single-Walled Carbon Nanotubes without a Metal Catalyst-A Surprising Discovery

2009 ◽  
Vol 48 (30) ◽  
pp. 5403-5404 ◽  
Author(s):  
Andreas Hirsch
2009 ◽  
Vol 131 (6) ◽  
pp. 2094-2095 ◽  
Author(s):  
Shaoming Huang ◽  
Qiran Cai ◽  
Jiangying Chen ◽  
Yong Qian ◽  
Lijie Zhang

2009 ◽  
Vol 131 (6) ◽  
pp. 2082-2083 ◽  
Author(s):  
Bilu Liu ◽  
Wencai Ren ◽  
Libo Gao ◽  
Shisheng Li ◽  
Songfeng Pei ◽  
...  

2013 ◽  
Vol 15 (16) ◽  
pp. 5992 ◽  
Author(s):  
Barbara Pacakova Bittova ◽  
Martin Kalbac ◽  
Simona Kubickova ◽  
Alice Mantlikova ◽  
Stephen Mangold ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2984
Author(s):  
Marianna V. Kharlamova ◽  
Christian Kramberger

We have investigated the effects of temperature, diameter and metal catalyst type on the growth of inner nanotubes inside metallocene-filled single-walled carbon nanotubes (SWCNTs). The effects on the yield of different chiralities of inner nanotubes were scrutinized by multifrequency Raman spectroscopy. The investigated diameters range from ~0.7 to 1.3 nm and comprise 36 distinct chiralities. For all three investigated metals (Ni, Co, Fe), there is a linear correlation of growth temperature with nanotube diameter. The common slope for these metals is found to be 40.5 °C/Å. The temperature difference between the largest and the smallest diameter tubes amounts to ~230 °C for all three precursors. The growth temperatures are offset by 34 °C from Ni to Co and another 28 °C from Co to Fe. The quantified correlations of temperature, diameter and metal catalyst type provide the basis for engineering the diameter-specific growth of nanotubes.


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