Cover Picture: In Situ Synchrotron-Based IR Microspectroscopy To Study Catalytic Reactions in Zeolite Crystals (Angew. Chem. Int. Ed. 19/2008)

2008 ◽  
Vol 47 (19) ◽  
pp. 3469-3469
Author(s):  
Eli Stavitski ◽  
Marianne H. F. Kox ◽  
Ingmar Swart ◽  
Frank M. F. de Groot ◽  
Bert M. Weckhuysen
Keyword(s):  
Catalytic Reactions ◽  
Ir Microspectroscopy ◽  
Zeolite Crystals

Titelbild: In Situ Synchrotron-Based IR Microspectroscopy To Study Catalytic Reactions in Zeolite Crystals (Angew. Chem. 19/2008)

2008 ◽  
Vol 120 (19) ◽  
pp. 3521-3521
Author(s):  
Eli Stavitski ◽  
Marianne H. F. Kox ◽  
Ingmar Swart ◽  
Frank M. F. de Groot ◽  
Bert M. Weckhuysen
Keyword(s):  
Catalytic Reactions ◽  
Ir Microspectroscopy ◽  
Zeolite Crystals

scholarly journals In Situ Synchrotron-Based IR Microspectroscopy To Study Catalytic Reactions in Zeolite Crystals

2008 ◽  
Vol 120 (19) ◽  
pp. 3599-3603 ◽  
Author(s):  
Eli Stavitski ◽  
Marianne H. F. Kox ◽  
Ingmar Swart ◽  
Frank M. F. de Groot ◽  
Bert M. Weckhuysen
Keyword(s):  
Catalytic Reactions ◽  
Ir Microspectroscopy ◽  
Zeolite Crystals

scholarly journals In Situ Synchrotron-Based IR Microspectroscopy To Study Catalytic Reactions in Zeolite Crystals

2008 ◽  
Vol 47 (19) ◽  
pp. 3543-3547 ◽  
Author(s):  
Eli Stavitski ◽  
Marianne H. F. Kox ◽  
Ingmar Swart ◽  
Frank M. F. de Groot ◽  
Bert M. Weckhuysen
Keyword(s):  
Catalytic Reactions ◽  
Ir Microspectroscopy ◽  
Zeolite Crystals

FT-IR microspectroscopic analysis of diseased white matter brain tissues

1995 ◽  
Vol 53 ◽  
pp. 968-969
Author(s):  
Steven M. Le Vine ◽  
David L. Wetzel
Keyword(s):  
White Matter ◽  
Gray Matter ◽  
Twitcher Mouse ◽  
Grid Pattern ◽  
Marked Contrast ◽  
Spatially Resolved ◽  
Ft Ir ◽  
Ir Microspectroscopy ◽  
Chemical Evidence

In situ FT-IR microspectroscopy has allowed spatially resolved interrogation of different parts of brain tissue. In previous work the spectrrscopic features of normal barin tissue were characterized. The white matter, gray matter and basal ganglia were mapped from appropriate peak area measurements from spectra obtained in a grid pattern. Bands prevalent in white matter were mostly associated with the lipid. These included 2927 and 1469 cm-1 due to CH2 as well as carbonyl at 1740 cm-1. Also 1235 and 1085 cm-1 due to phospholipid and galactocerebroside, respectively (Figs 1and2). Localized chemical changes in the white matter as a result of white matter diseases have been studied. This involved the documentation of localized chemical evidence of demyelination in shiverer mice in which the spectra of white matter lacked the marked contrast between it and gray matter exhibited in the white matter of normal mice (Fig. 3).The twitcher mouse, a model of Krabbe’s desease, was also studied. The purpose in this case was to look for a localized build-up of psychosine in the white matter caused by deficiencies in the enzyme responsible for its breakdown under normal conditions.

The electron-transfer intermediates of the oxygen evolution reaction (OER) as polarons by in situ spectroscopy

2021 ◽  
Author(s):  
Hanna Lyle ◽  
Suryansh Singh ◽  
Michael Paolino ◽  
Ilya Vinogradov ◽  
Tanja Cuk
Keyword(s):  
Electron Transfer ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Catalytic Reactions ◽  
In Situ Spectroscopy ◽  
Chemical Bonds

The conversion of diffusive forms of energy (electrical and light) into short, compact chemical bonds by catalytic reactions regularly involves moving a carrier from an environment that favors delocalization to one that favors localization.

In situ loading of well-dispersed silver nanoparticles on nanocrystalline magnesium oxide for real-time monitoring of catalytic reactions by surface enhanced Raman spectroscopy

Nanoscale ◽  
2015 ◽  
Vol 7 (40) ◽  
pp. 16952-16959 ◽  
Author(s):  
Kaige Zhang ◽  
Gongke Li ◽  
Yuling Hu
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Catalytic Reactions ◽  
Reaction Intermediates ◽  
Reaction Conditions ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Nanocrystalline Magnesium Oxide ◽  
Insight Into

The surface-enhanced Raman spectroscopy (SERS) technique is of great importance for insight into the transient reaction intermediates and mechanistic pathways involved in heterogeneously catalyzed chemical reactions under actual reaction conditions, especially in water.

57Fe Mössbauer Spectroscopic Study of the Geometrical Effects In the Catalytic Reactions with Intercalation Compounds

1982 ◽  
Vol 20 ◽  
Author(s):  
P.P. Vaishnava ◽  
P.A. Montano
Keyword(s):  
Ferric Chloride ◽  
Catalytic Reactions ◽  
Fischer Tropsch ◽  
Reaction Conditions ◽  
Intercalated Graphite ◽  
The Third ◽  
Intercalated Compounds ◽  
Catalytic Sites ◽  
Geometrical Effects

ABSTRACTIn situ 57Fe Mössbauer spectra are reported for the first-, higher-stage ferric chloride, and a mixed ferric chloride-potassium chloride intercalated graphite catalysts under reduction and Fischer-Tropsch reaction conditions. The mass spectroscopic measurements reveal a different catalytic selectivity for the three catalysts. The first two catalysts predominantly possess a higher selectivity for methane, whereas the third catalyst has higher selectivity for the formation of propane. The differences are attributed to geometrical effects in the catalytic sites of the intercalated compounds.

Electrochemically controlled in-situ conversion of CO2 to defective carbon nanotubes for enhanced H2O2 production

Nanoscale ◽  
2021 ◽  
Author(s):  
Ao Yu ◽  
Guoming Ma ◽  
Longtao Zhu ◽  
Yajing Hu ◽  
Ruiling Zhang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Active Sites ◽  
Catalytic Reactions ◽  
H2o2 Production

Defects on carbon nanotubes (CNTs) can be used as active sites to promote the occurrence of catalytic reactions and improve the ability of catalysts. Although some progress has been made...

scholarly journals Detailed investigations of the influence of catalyst packing porosity on the performance of THAI-CAPRI process for in situ catalytic upgrading of heavy oil and bitumen

2021 ◽  
Author(s):  
Muhammad Rabiu Ado
Keyword(s):  
Oil Production ◽  
Accessible Surface Area ◽  
Mitigation Strategies ◽  
Catalytic Reactions ◽  
Heavy Oils ◽  
World Energy ◽  
Catalyst Life ◽  
Free Transition ◽  
Accessible Surface

AbstractHeavy oils and bitumen are indispensable resources for a turbulent-free transition to a decarbonized global energy and economic system. This is because according to the analysis of the International Energy Agency’s 2020 estimates, the world requires up to 770 billion barrels of oil from now to year 2040. However, BP’s 2020 statistical review of world energy has shown that the global total reserves of the cheap-to-produce conventional oil are roughly only 520.2 billion barrels. This implies that the huge reserves of the practically unexploited difficult-and-costly-to-upgrade-and-produce heavy oils and bitumen must be immediately developed using advanced upgrading and extraction technologies which have greener credentials. Furthermore, in accordance with climate change mitigation strategies and to efficiently develop the heavy oils and bitumen resources, producers would like to maximize their upgrading within the reservoirs by using energy-efficient and environmentally friendly technologies such as the yet-to-be-fully-understood THAI-CAPRI process. The THAI-CAPRI process uses in situ combustion and in situ catalytic reactions to produce high-quality oil from heavy oils and bitumen reservoirs. However, prolonging catalyst life and effectiveness and maximizing catalytic reactions are a major challenge in the THAI-CAPRI process. Therefore, in this work, the first ever-detailed investigations of the effects of alumina-supported cobalt oxide–molybdenum oxide (CoMo/γ-Al2O3) catalyst packing porosity on the performance of the THAI-CAPRI process are performed through numerical simulations using CMG STARS. The key findings in this study include: the larger the catalyst packing porosity, the higher the accessible surface area for the mobilized oil to reach the inner coke-uncoated catalysts and thus the higher the API gravity and quality of the produced oil, which clearly indicated that sulphur and nitrogen heteroatoms were catalytically removed and replaced with hydrogen. Over the 290 min of combustion period, slightly more oil (i.e. an additional 0.43% oil originally in place (OOIP)) is recovered in the model which has the higher catalyst packing porosity. In other words, there is a cumulative oil production of 2330 cm3 when the catalyst packing porosity is 56% versus a cumulative oil production of 2300 cm3 in the model whose catalyst packing porosity is 45%. The larger the catalyst packing porosity, the lower the mass and thus cost of the catalyst required per m3 of annular space around the horizontal producer well. The peak temperature and the very small amount of produced oxygen are only marginally affected by the catalyst packing porosity, thereby implying that the extents of the combustion and thermal cracking reactions are respectively the same in both models. Thus, the higher upgrading achieved in the model whose catalyst packing porosity is 56% is purely due to the fact that the extent of the catalytic reactions in the model is larger than those in the model whose catalyst packing porosity is 45%.

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