Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation-Isomerization Pathway

2008 ◽  
Vol 47 (35) ◽  
pp. 6638-6642 ◽  
Author(s):  
Gaoxi Jiang ◽  
Jian Chen ◽  
Hung-Yat Thu ◽  
Jie-Sheng Huang ◽  
Nianyong Zhu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Isomerization Pathway ◽  
Ruthenium Porphyrin

ChemInform Abstract: Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation-Isomerization Pathway.

ChemInform ◽  
2008 ◽  
Vol 39 (50) ◽  
Author(s):  
Gaoxi Jiang ◽  
Jian Chen ◽  
Hung-Yat Thu ◽  
Jie-Sheng Huang ◽  
Nianyong Zhu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Isomerization Pathway ◽  
Ruthenium Porphyrin

Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation-Isomerization Pathway

2008 ◽  
Vol 120 (35) ◽  
pp. 6740-6744 ◽  
Author(s):  
Gaoxi Jiang ◽  
Jian Chen ◽  
Hung-Yat Thu ◽  
Jie-Sheng Huang ◽  
Nianyong Zhu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Isomerization Pathway ◽  
Ruthenium Porphyrin

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Oxidase Catalysis via an Aerobically Generated Dess-Martin Periodinane Analogue

2018 ◽  
Author(s):  
Asim Maity ◽  
Sung-Min Hyun ◽  
Alan Wortman ◽  
David Powers
Keyword(s):  
Chemical Synthesis ◽  
Aerobic Oxidation ◽  
Substrate Oxidation ◽  
Oxidation Catalysis ◽  
Hypervalent Iodine ◽  
Oxidation Reactions ◽  
Broad Array ◽  
Oxidation Chemistry ◽  
Reactive Oxidants

<p>Hypervalent iodine(V) reagents, such as Dess-Martin periodinane (DMP) and 2-iodoxybenzoic acid (IBX), are broadly useful oxidants in chemical synthesis. Development of strategies to access these reagents from O2 would immediately enable use of O2 as a terminal oxidant in a broad array of substrate oxidation reactions. Recently we disclosed the aerobic synthesis of I(III) reagents by intercepting reactive oxidants generated during aldehyde autoxidation. Here, we couple aerobic oxidation of iodobenzenes with disproportionation of the initially generated I(III) compounds to generate I(V) reagents. The aerobically generated I(V) reagents exhibit substrate oxidation chemistry analogous to that of DMP. Further, the developed aerobic generation of I(V) has enabled the first application of I(V) intermediates in aerobic oxidation catalysis.</p>

Recent Development in Aerobic Oxidation of Amines

2012 ◽  
Vol 9 (3) ◽  
pp. 319-340
Author(s):  
Bo-Tao Xin ◽  
Qing-Fa Zhou ◽  
Tao Lu
Keyword(s):  
Aerobic Oxidation

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

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