A Highly Stereoselective Hydrogen-Bond-Mediated Michael–Michael Cascade Process through Dynamic Kinetic Resolution

2008 ◽  
Vol 47 (22) ◽  
pp. 4177-4179 ◽  
Author(s):  
Jian Wang ◽  
Hexin Xie ◽  
Hao Li ◽  
Liansuo Zu ◽  
Wei Wang
Keyword(s):  
Hydrogen Bond ◽  
Kinetic Resolution ◽  
Cascade Process ◽  
Dynamic Kinetic Resolution

A Highly Stereoselective Hydrogen-Bond-Mediated Michael–Michael Cascade Process through Dynamic Kinetic Resolution

2008 ◽  
Vol 120 (22) ◽  
pp. 4245-4247 ◽  
Author(s):  
Jian Wang ◽  
Hexin Xie ◽  
Hao Li ◽  
Liansuo Zu ◽  
Wei Wang
Keyword(s):  
Hydrogen Bond ◽  
Kinetic Resolution ◽  
Cascade Process ◽  
Dynamic Kinetic Resolution

scholarly journals Racemic hemiacetals as oxygen-centered pronucleophiles triggering cascade 1,4-addition/Michael reaction through dynamic kinetic resolution under iminium catalysis. Development and mechanistic insights

2017 ◽  
Vol 8 (4) ◽  
pp. 2904-2913 ◽  
Author(s):  
Ane Orue ◽  
Uxue Uria ◽  
David Roca-López ◽  
Ignacio Delso ◽  
Efraím Reyes ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Michael Reaction ◽  
Conjugate Addition ◽  
Cascade Process ◽  
Dynamic Kinetic Resolution ◽  
Single Stereoisomer

Racemic 2-hydroxydihydropyran-5-ones react as unconventional O-pronucleophiles in a conjugate addition/Michael reaction cascade process under DKR, leading to the formation of a single stereoisomer out of 16 possible ones.

scholarly journals Hydrogen‐Bond‐Enabled Dynamic Kinetic Resolution of Axially Chiral Amides Mediated by a Chiral Counterion

2019 ◽  
Vol 58 (9) ◽  
pp. 2795-2798 ◽  
Author(s):  
Alison J. Fugard ◽  
Antti S. K. Lahdenperä ◽  
Jaqueline S. J. Tan ◽  
Aroonroj Mekareeya ◽  
Robert S. Paton ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Axially Chiral

scholarly journals Hydrogen‐Bond‐Enabled Dynamic Kinetic Resolution of Axially Chiral Amides Mediated by a Chiral Counterion

2019 ◽  
Vol 131 (9) ◽  
pp. 2821-2824 ◽  
Author(s):  
Alison J. Fugard ◽  
Antti S. K. Lahdenperä ◽  
Jaqueline S. J. Tan ◽  
Aroonroj Mekareeya ◽  
Robert S. Paton ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Axially Chiral
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