Mixed Spin-State [HS-LS] Pairs in a Dinuclear Spin-Transition Complex: Confirmation by Variable-Temperature57Fe Mössbauer Spectroscopy

2008 ◽  
Vol 47 (16) ◽  
pp. 2997-2999 ◽  
Author(s):  
C. Matthias Grunert ◽  
Sergey Reiman ◽  
Hartmut Spiering ◽  
Jonathan A. Kitchen ◽  
Sally Brooker ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Spin State ◽  
Mossbauer Spectroscopy ◽  
Spin Transition ◽  
Mößbauer Spectroscopy ◽  
Mixed Spin ◽  
Transition Complex

Mixed Spin-State [HS-LS] Pairs in a Dinuclear Spin-Transition Complex: Confirmation by Variable-Temperature57Fe Mössbauer Spectroscopy

2008 ◽  
Vol 120 (16) ◽  
pp. 3039-3041 ◽  
Author(s):  
C. Matthias Grunert ◽  
Sergey Reiman ◽  
Hartmut Spiering ◽  
Jonathan A. Kitchen ◽  
Sally Brooker ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Spin State ◽  
Mossbauer Spectroscopy ◽  
Spin Transition ◽  
Mößbauer Spectroscopy ◽  
Mixed Spin ◽  
Transition Complex

Titelbild: Mixed Spin-State [HS-LS] Pairs in a Dinuclear Spin-Transition Complex: Confirmation by Variable-Temperature57Fe Mössbauer Spectroscopy (Angew. Chem. 16/2008)

2008 ◽  
Vol 120 (16) ◽  
pp. 2935-2935
Author(s):  
C. Matthias Grunert ◽  
Sergey Reiman ◽  
Hartmut Spiering ◽  
Jonathan A. Kitchen ◽  
Sally Brooker ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Spin State ◽  
Mossbauer Spectroscopy ◽  
Spin Transition ◽  
Mößbauer Spectroscopy ◽  
Mixed Spin ◽  
Transition Complex

scholarly journals A Synchrotron Mössbauer Spectroscopy Study of a Hydrated Iron-Sulfate at High Pressures

Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 146
Author(s):  
Tyler Perez ◽  
Gregory J. Finkelstein ◽  
Olivia Pardo ◽  
Natalia V. Solomatova ◽  
Jennifer M. Jackson
Keyword(s):  
Mössbauer Spectroscopy ◽  
Ferrous Iron ◽  
High Pressures ◽  
Mossbauer Spectroscopy ◽  
Spin Transition ◽  
Iron Sulfate ◽  
Helium Pressure ◽  
Powdered Sample ◽  
Mößbauer Spectroscopy ◽  
Electronic Environment

Szomolnokite is a monohydrated ferrous iron sulfate mineral, FeSO4·H2O, where the ferrous iron atoms are in octahedral coordination with four corners shared with SO4 and two with H2O groups. While somewhat rare on Earth, szomolnokite has been detected on the surface of Mars along with several other hydrated sulfates and is suggested to occur near the surface of Venus. Previous measurements have characterized the local environment of the iron atoms in szomolnokite using Mössbauer spectroscopy at a range of temperatures and 1 bar. Our study represents a step towards understanding the electronic environment of iron in szomolnokite under compression at 300 K. Using a hydrostatic helium pressure-transmitting medium, we explored the pressure dependence of iron’s site-specific behavior in a synthetic szomolnokite powdered sample up to 95 GPa with time-domain synchrotron Mössbauer spectroscopy. At 1 bar, the Mössbauer spectrum is well described by two Fe2+-like sites and no ferric iron, consistent with select conventional Mössbauer spectra evaluations. At pressures below 19 GPa, steep gradients in the hyperfine parameters are most likely due to a structural phase transition. At 19 GPa, a fourth site is required to explain the time spectrum with increasing fractions of a low quadrupole splitting site, which could indicate the onset of another transition. Above 19 GPa we present three different models, including those with a high- to low-spin transition, that provide reasonable scenarios of electronic environment changes of the iron in szomolnokite with pressure. We summarize the complex range of Fe2+ spin transition characteristics at high-pressures by comparing szomolnokite with previous studies on ferrous-iron bearing phases.

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