Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study

2008 ◽  
Vol 47 (22) ◽  
pp. 4100-4105 ◽  
Author(s):  
Franck Millange ◽  
Christian Serre ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Richard I. Walton
Keyword(s):  
Diffraction Study ◽  
Metal Organic Frameworks ◽  
Structural Effects ◽  
Metal Organic ◽  
In Situ Diffraction

Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study

2008 ◽  
Vol 120 (22) ◽  
pp. 4168-4173 ◽  
Author(s):  
Franck Millange ◽  
Christian Serre ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Richard I. Walton
Keyword(s):  
Diffraction Study ◽  
Metal Organic Frameworks ◽  
Structural Effects ◽  
Metal Organic ◽  
In Situ Diffraction

Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks

2009 ◽  
Vol 122 (4) ◽  
pp. 775-778 ◽  
Author(s):  
Franck Millange ◽  
Manuela I. Medina ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Kathryn M. Golden ◽  
...  
Keyword(s):  
Diffraction Study ◽  
Metal Organic Frameworks ◽  
Time Resolved ◽  
Metal Organic ◽  
In Situ Diffraction

scholarly journals Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks

2009 ◽  
Vol 49 (4) ◽  
pp. 763-766 ◽  
Author(s):  
Franck Millange ◽  
Manuela I. Medina ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Kathryn M. Golden ◽  
...  
Keyword(s):  
Diffraction Study ◽  
Metal Organic Frameworks ◽  
Time Resolved ◽  
Metal Organic ◽  
In Situ Diffraction

scholarly journals In situ X‐ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce(IV)‐based Metal‐Organic Frameworks with UiO‐66 and MIL‐140 architectures

2021 ◽  
Author(s):  
Stephen J. I. Shearan ◽  
Jannick Jacobsen ◽  
Ferdinando Costantino ◽  
Roberto D’Amato ◽  
Dmitri Novikov ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic

scholarly journals Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 722
Author(s):  
Ioanna Christodoulou ◽  
Tom Bourguignon ◽  
Xue Li ◽  
Gilles Patriarche ◽  
Christian Serre ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Degradation Mechanism ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Force Microscopy ◽  
Atomic Force ◽  
Metal Organic ◽  
The Media ◽  
Ph Conditions

In recent years, Metal-Organic Frameworks (MOFs) have attracted a growing interest for biomedical applications. The design of MOFs should take into consideration the subtle balance between stability and biodegradability. However, only few studies have focused on the MOFs’ stability in physiological media and their degradation mechanism. Here, we investigate the degradation of mesoporous iron (III) carboxylate MOFs, which are among the most employed MOFs for drug delivery, by a set of complementary methods. In situ AFM allowed monitoring with nanoscale resolution the morphological, dimensional, and mechanical properties of a series of MOFs in phosphate buffer saline and in real time. Depending on the synthetic route, the external surface presented either well-defined crystalline planes or initial defects, which influenced the degradation mechanism of the particles. Moreover, MOF stability was investigated under different pH conditions, from acidic to neutral. Interestingly, despite pronounced erosion, especially at neutral pH, the dimensions of the crystals were unchanged. It was revealed that the external surfaces of MOF crystals rapidly respond to in situ changes of the composition of the media they are in contact with. These observations are of a crucial importance for the design of nanosized MOFs for drug delivery applications.

In-situ growth of ZIF-8 on gold nanoparticles/magnetic carbon nanotubes for electrochemical detection of bisphenol A

2021 ◽  
Author(s):  
Hexiang Li ◽  
Fawei Zhu ◽  
Jun Xiang ◽  
Fangbin Wang ◽  
Qi Liu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Gold Nanoparticles ◽  
Bisphenol A ◽  
Electrochemical Detection ◽  
Metal Organic Frameworks ◽  
In Situ Growth ◽  
Metal Organic ◽  
Magnetic Carbon ◽  
Magnetic Carbon Nanotubes

We herein report a facile and scalable strategy for fabrication of the metal organic frameworks (MOFs) based composite by in-situ growing ZIF-8 on the gold nanoparticles (AuNPs) loaded magnetic carbon...

Development of Au-Pd@UiO-66-on-ZIF-L/CC as a self-supported electrochemical sensor for in situ monitoring of cellular hydrogen peroxide

2021 ◽  
Author(s):  
Jilin Zheng ◽  
Peng Zhao ◽  
Shiying Zhou ◽  
Sha Chen ◽  
Yi Liang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Electrochemical Sensor ◽  
Noble Metals ◽  
Electrochemical Sensors ◽  
Metal Organic Frameworks ◽  
Electrochemical Sensing ◽  
In Situ Monitoring ◽  
Metal Organic

Integrating metal-organic frameworks (MOFs) of different components or structures together and exploiting them as electrochemical sensors for electrochemical sensing have aroused great interest. And the incorporation of noble metals with...

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