A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus

2006 ◽  
Vol 45 (25) ◽  
pp. 4182-4185 ◽  
Author(s):  
Dmitry Yakhvarov ◽  
Pierluigi Barbaro ◽  
Luca Gonsalvi ◽  
Sonia Mañas Carpio ◽  
Stefano Midollini ◽  
...  
Keyword(s):  
White Phosphorus

Fragmentation, Catenation, and Direct Functionalisation of White Phosphorus by a Uranium(IV)-Silyl-Phosphino-Carbene Complex

2021 ◽  
Author(s):  
Josef Boronski ◽  
John Seed ◽  
Ashley Wooles ◽  
Stephen Liddle
Keyword(s):  
Room Temperature ◽  
White Phosphorus ◽  
Temperature Reaction ◽  
Carbene Complex

Room temperature reaction of the uranium(IV)-carbene [U{C(SiMe3)(PPh2)}(BIPMTMS)(μ-Cl)Li(TMEDA)(μ-TMEDA)0.5]2 (1, BIPMTMS = C(PPh2NSiMe3)2) with white phosphorus (P4) produces the organo-P5 compound [P5{C(SiMe3)(PPh2)}2][Li(TMEDA)2] (2) and the uranium(IV)-methanediide [U{BIPMTMS}{Cl}{μ-Cl}2{Li(TMEDA)}] (3). This is an unprecedented...

Formation of palladium phosphides in the reaction of bis(dibenzylideneacetone)palladium(0) with white phosphorus

2012 ◽  
Vol 82 (2) ◽  
pp. 206-211 ◽  
Author(s):  
N. I. Skripov ◽  
L. B. Belykh ◽  
L. N. Belonogova ◽  
A. V. Rokhin ◽  
T. P. Stepanova ◽  
...  
Keyword(s):  
White Phosphorus

Risk assessment of white phosphorus in military training areas, a probabilistic approach

2006 ◽  
Vol 164 ◽  
pp. S139-S140 ◽  
Author(s):  
Øyvind Albert Voie ◽  
Kjetil S. Longva ◽  
Arnljot E. Strømseng ◽  
Arnt Johnsen
Keyword(s):  
Risk Assessment ◽  
Military Training ◽  
Probabilistic Approach ◽  
White Phosphorus ◽  
Military Training Areas

Evidence for chemical burns by white phosphorus in Armenian soldiers during the 2020 Nagorno-Karabakh war

Injury ◽  
2021 ◽  
Vol 52 (4) ◽  
pp. 1100-1101
Author(s):  
Son Brutyan ◽  
Karine Babayan ◽  
Nazi Barseghyan ◽  
Vahagn Petrosyan ◽  
Patrick Knipper ◽  
...  
Keyword(s):  
White Phosphorus ◽  
Chemical Burns

An analytical method to identify traces of white phosphorus on burned victim clothes

2017 ◽  
Vol 280 ◽  
pp. 224-227 ◽  
Author(s):  
Dan Muller ◽  
Yaniv Y. Avissar ◽  
Sarit Kimchi ◽  
Arnon Grafit
Keyword(s):  
Analytical Method ◽  
White Phosphorus

Atomvolumen, Packungsdichte der Atome und chemische Bindung in nichtmetallischen Elementen

2007 ◽  
Vol 63 (4) ◽  
pp. 532-536 ◽  
Author(s):  
M. Trömel
Keyword(s):  
Packing Density ◽  
Additional Assumption ◽  
White Phosphorus ◽  
Atomic Volume

The atomic volume of crystalline elements is largely determined by the packing density of atoms in the respective modification. The determination of packing density is improved by assuming that the atomic distances depend on bond valences according to Pauling's equation. With the additional assumption of equal valence in different modifications, the experimental atomic volume of an element in any given structure is reduced to its volume in close-packed structures, e.g. f.c.c. The ratio of this reduced atomic volume and the experimental atomic volume is a measure of packing density. Reduced atomic volumes of C, Si, Ge, P, As, S and Se, as calculated from different modifications, correspond in most cases to within less than ±1% for each element, even if calculated from extremely different structures like diamond and buckminsterfullerene in the case of carbon, or from numerous modifications of sulfur with annular molecules of different sizes. Exceptions (graphite, white phosphorus, tin and selenium) indicate deviating valences.

Crystal growth morphology in high purity white phosphorus

1977 ◽  
Vol 37 (1) ◽  
pp. 64-68 ◽  
Author(s):  
J.D. Ayers ◽  
R.J. Schaefer ◽  
M.E. Glicksman
Keyword(s):  
Crystal Growth ◽  
High Purity ◽  
White Phosphorus ◽  
Growth Morphology

Phosphafluorenyl lithiums: direct synthesis from white phosphorus, structure and diversified synthons

2021 ◽  
Author(s):  
Jingyuan Hu ◽  
Zhengqi Chai ◽  
Wei Liu ◽  
Zhe Huang ◽  
Junnian Wei ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
White Phosphorus
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