Oxidative Addition of NH3 to a Transition-Metal Complex: A Key Step for the Metal-Mediated Derivatization of Ammonia?

2005 ◽  
Vol 44 (32) ◽  
pp. 5012-5014 ◽  
Author(s):  
Thomas Braun
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Oxidative Addition

Oxidative addition of Bi–C bonds to Pt(0): reaction of Pt(PEt3)3 with cyclic organobismuth compounds

2020 ◽  
Vol 56 (96) ◽  
pp. 15216-15219
Author(s):  
Shigeru Shimada ◽  
Xiang-Bo Wang ◽  
Masato Tanaka
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Oxidative Addition ◽  
First Time

Oxidative addition of a Bi–C bond to a transition metal complex was demonstrated for the first time.

scholarly journals Iridium-catalyzed borylation of arenes and heteroarenes via C-H activation

2006 ◽  
Vol 78 (7) ◽  
pp. 1369-1375 ◽  
Author(s):  
Tatsuo Ishiyama ◽  
Norio Miyaura
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Aromatic Compounds ◽  
Transition Metal Complex ◽  
Oxidative Addition ◽  
Catalytic Cycle ◽  
Iridium Complexes

Direct C-H borylation of aromatic compounds catalyzed by a transition-metal complex was studied as an economical protocol for the synthesis of aromatic boron derivatives. Iridium complexes generated from Ir(I) precursors and 2,2'-bipyridine ligands efficiently catalyzed the reactions of arenes and heteroarenes with bis(pinacolato)diboron or pinacolborane to produce a variety of aryl- and heteroarylboron compounds. The catalytic cycle involves the formation of a tris(boryl)iridium(III) species and its oxidative addition to an aromatic C-H bond.

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