Diastereoselective Synthesis of Cycloheptadienol Derivatives by a Formal [5+2] Carbocyclization Reaction of α,β,γ,δ-Diunsaturated (Methoxy)carbene Complexes with Methyl Ketone Lithium Enolates

José Barluenga; Jorge Alonso; Francisco J. Fañanás; Javier Borge; Santiago García-Granda

doi:10.1002/anie.200460547

Diastereoselective Synthesis of Cycloheptadienol Derivatives by a Formal [5+2] Carbocyclization Reaction of α,β,γ,δ-Diunsaturated (Methoxy)carbene Complexes with Methyl Ketone Lithium Enolates

Angewandte Chemie International Edition ◽

10.1002/anie.200460547 ◽

2004 ◽

Vol 43 (41) ◽

pp. 5510-5513 ◽

Cited By ~ 15

Author(s):

José Barluenga ◽

Jorge Alonso ◽

Francisco J. Fañanás ◽

Javier Borge ◽

Santiago García-Granda

Keyword(s):

Methyl Ketone ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

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Solvent-Controlled Diastereoselective Synthesis of Cyclopentane Derivatives by a [3 + 2] Cyclization Reaction of α,β-Disubstituted (Alkenyl)(methoxy)carbene Complexes with Methyl Ketone Lithium Enolates

Journal of the American Chemical Society ◽

10.1021/ja029170x ◽

2003 ◽

Vol 125 (9) ◽

pp. 2610-2616 ◽

Cited By ~ 25

Author(s):

José Barluenga ◽

Jorge Alonso ◽

Francisco J. Fañanás

Keyword(s):

Methyl Ketone ◽

Cyclization Reaction ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

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Diastereoselective Synthesis of Cycloheptadienol Derivatives by a Formal [5 + 2] Carbocyclization Reaction of α,β,γ,δ-Diunsaturated (Methoxy)carbene Complexes with Methyl Ketone Lithium Enolates.

ChemInform ◽

10.1002/chin.200506076 ◽

2005 ◽

Vol 36 (6) ◽

Author(s):

Jose Barluenga ◽

Jorge Alonso ◽

Francisco J. Fananas ◽

Javier Borge ◽

Santiago Garcia-Granda

Keyword(s):

Methyl Ketone ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

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Diastereoselective Synthesis of Five- and Seven-Membered Rings by [2 + 2 + 1], [3 + 2], [3 + 2 + 2], and [4 + 3] Carbocyclization Reactions of β-Substituted (Alkenyl)(methoxy)carbene Complexes with Methyl Ketone Lithium Enolates.

ChemInform ◽

10.1002/chin.200612039 ◽

2006 ◽

Vol 37 (12) ◽

Author(s):

Jose Barluenga ◽

Jorge Alonso ◽

Francisco J. Fananas

Keyword(s):

Methyl Ketone ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

Download Full-text

Diastereoselective Synthesis of Five- and Seven-Membered Rings by [2+2+1], [3+2], [3+2+2], and [4+3] Carbocyclization Reactions of β-Substituted (Alkenyl)(methoxy)carbene Complexes with Methyl Ketone Lithium Enolates

Chemistry - A European Journal ◽

10.1002/chem.200500164 ◽

2005 ◽

Vol 11 (17) ◽

pp. 4995-5006 ◽

Cited By ~ 16

Author(s):

José Barluenga ◽

Jorge Alonso ◽

Francisco J. Fañanás

Keyword(s):

Methyl Ketone ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

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Solvent-Controlled Diastereoselective Synthesis of Cyclopentane Derivatives by a [3 + 2] Cyclization Reaction of α,β-Disubstituted (Alkenyl)(methoxy)carbene Complexes with Methyl Ketone Lithium Enolates.

ChemInform ◽

10.1002/chin.200327032 ◽

2003 ◽

Vol 34 (27) ◽

Author(s):

Jose Barluenga ◽

Jorge Alonso ◽

Francisco J. Fananas

Keyword(s):

Methyl Ketone ◽

Cyclization Reaction ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

Download Full-text

Diastereoselective Synthesis of Cycloheptadienol Derivatives by a Formal [5+2] Carbocyclization Reaction of α,β,γ,δ-Diunsaturated (Methoxy)carbene Complexes with Methyl Ketone Lithium Enolates

Angewandte Chemie ◽

10.1002/ange.200460547 ◽

2004 ◽

Vol 116 (41) ◽

pp. 5626-5629 ◽

Cited By ~ 7

Author(s):

José Barluenga ◽

Jorge Alonso ◽

Francisco J. Fañanás ◽

Javier Borge ◽

Santiago García-Granda

Keyword(s):

Methyl Ketone ◽

Diastereoselective Synthesis ◽

Carbene Complexes ◽

Lithium Enolates

Download Full-text

Diastereoselective Synthesis of Three-, Five-, Six-, and Seven-Membered Rings from Fischer Carbene Complexes and 4-Unsubstituted 1-Amino-1,3-Dienes

Chemistry - A European Journal ◽

10.1002/chem.200701109 ◽

2007 ◽

Vol 14 (1) ◽

pp. 325-332 ◽

Cited By ~ 12

Author(s):

Fernando Aznar ◽

Martín Fañanás-Mastral ◽

Jorge Alonso ◽

Francisco J. Fañanás

Keyword(s):

Diastereoselective Synthesis ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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Three/Four/Five-Component Diastereoselective Cyclization of Fischer Carbene Complexes, Lithium Enolates, and Allylmagnesium Bromide.

ChemInform ◽

10.1002/chin.200412046 ◽

2004 ◽

Vol 35 (12) ◽

Author(s):

Jose Barluenga ◽

Ivan Perez-Sanchez ◽

Eduardo Rubio ◽

Josefa Florez

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Lithium Enolates

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First highly regio- and diastereoselective synthesis of Δ2-pyrazolines by [3+2] cycloaddition of chiral non-racemic Fischer carbene complexes with nitrilimines

Tetrahedron Letters ◽

10.1016/s0040-4039(98)00886-7 ◽

1998 ◽

Vol 39 (27) ◽

pp. 4887-4890 ◽

Cited By ~ 24

Author(s):

José Barluenga ◽

Félix Fernández-Marí ◽

Enrique Aguilar ◽

Argimiro L Viado ◽

Bernardo Olano

Keyword(s):

Diastereoselective Synthesis ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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Five- and Seven-Membered Rings from Alkenyl(methoxy)carbene Complexes and Methyl Ketone Enolates

Angewandte Chemie International Edition ◽

10.1002/1521-3773(20000717)39:14<2459::aid-anie2459>3.0.co;2-e ◽

2000 ◽

Vol 39 (14) ◽

pp. 2459-2462 ◽

Cited By ~ 28

Author(s):

José Barluenga ◽

Jorge Alonso ◽

Félix Rodríguez ◽

Francisco J. Fañanás

Keyword(s):

Methyl Ketone ◽

Carbene Complexes ◽

Ketone Enolates

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