Analysis of the Bonding in[Ni5(μ5-S)(μ2-SR)5]−, an Unprecedented Pentanuclear Sulfide Cluster

1997 ◽  
Vol 36 (17) ◽  
pp. 1847-1849 ◽  
Author(s):  
Fu-Wah Cheung ◽  
Zhenyang Lin
Keyword(s):  
Sulfide Cluster

A cobalt sulfide cluster-based catholyte for aqueous flow battery applications

2018 ◽  
Vol 6 (44) ◽  
pp. 21927-21932 ◽  
Author(s):  
Matthew B. Freeman ◽  
Le Wang ◽  
Daniel S. Jones ◽  
Christopher M. Bejger
Keyword(s):  
Active Material ◽  
Water Soluble ◽  
Molecular Cluster ◽  
Cobalt Sulfide ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Aqueous Flow ◽  
Sulfide Cluster

A water-soluble Co6S8 molecular cluster was prepared and electrochemically analyzed as a potential active material for redox flow battery applications.

Reactivity of an Arene Cobalt Triple Decker Complex Towards Various Ligands. Facile Arene Displacement in [Bis{( η5-pentamethylcyclopentadienyl)cobalt}-μ-{η4: η4-toluene}]

1995 ◽  
Vol 50 (7) ◽  
pp. 1055-1060 ◽  
Author(s):  
Jörg J. Schneider
Keyword(s):  
Room Temperature ◽  
Elemental Sulfur ◽  
Organic Ligands ◽  
Dinuclear Complexes ◽  
Sulfide Cluster

The triple decker complex [{(η5-Cp*)Co}2-μ-{η4: η4-toluene}] 1b exhibits an unusual reactivity towards a variety of organic ligands, 1b reacts with CO, ethene, butadiene, H2, Al2O3, hexafluorobenzene, 1.5 Cod, 2-butyne, phenanthrene, naphthalene and the dinuclear Ni cluster [{(η5-Cp)NiP(C2H5)3}2] to form mainly mononuclear organocobalt complexes. Reaction of 1b with NO and the diazoalkanes di-t-butyl-diazomethane and 2-diazo-1,1′,3,3′-tetramethylcyclohexane results in the formation of the dinuclear complexes [{(η5-Cp*)CoNO}2], [{(η5-Cp*)(di-t-butyl-diazomethane)Co}2] and [{(η5-Cp*)(2-diazo-1,1′,3,3′-tetramethylcyclohexane) Co}2], respectively. In the reaction of 1b with elemental sulfur the formation of a tetranuclear Co-sulfide cluster is observed. In the majority of the reactions studied, l b looses its toluene ligand already at room temperature indicating an unusual high and hitherto unprecedented reactivity of an arene triple decker complex.

Hydrogen evolution from water reactions with molybdenum sulfide cluster anions

2018 ◽  
Vol 434 ◽  
pp. 193-201 ◽  
Author(s):  
Josey E. Topolski ◽  
Ankur K. Gupta ◽  
Kathleen A. Nickson ◽  
Krishnan Raghavachari ◽  
Caroline Chick Jarrold
Keyword(s):  
Hydrogen Evolution ◽  
Molybdenum Sulfide ◽  
Cluster Anions ◽  
Sulfide Cluster

Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry

1995 ◽  
Vol 6 (3) ◽  
pp. 421-436 ◽  
Author(s):  
Seiji Ogo ◽  
Takayoshi Suzuki ◽  
Sachiyo Nomura ◽  
Kiyotaka Asakura ◽  
Kiyoshi Isobe
Keyword(s):  
Mass Spectrometry ◽  
Fast Atom Bombardment ◽  
Linear Type ◽  
Sulfide Cluster

Sulfide cluster vacancies inducing an electrochemical reversibility improvement of titanium disulfide electrode material

2020 ◽  
Vol 8 (14) ◽  
pp. 6532-6538
Author(s):  
Jianhao Lu ◽  
Fang Lian ◽  
Yuxuan Zhang ◽  
Ning Chen ◽  
Yang Li ◽  
...  
Keyword(s):  
Electrode Material ◽  
Structural Integrity ◽  
Lithium Ions ◽  
Titanium Disulfide ◽  
Electrochemical Reversibility ◽  
Sulfide Cluster

CV–TiS2−x exhibits an extended planar spacing and structural integrity in a process involving more lithium ions due to the presence of abundant S-vacancies.

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