Computer Graphics in the Study of Metal Cluster Compounds

Kim Henrick; Mary McPartlin; Jill Morris

doi:10.1002/anie.198608533

Computer Graphics in the Study of Metal Cluster Compounds

Angewandte Chemie International Edition in English ◽

10.1002/anie.198608533 ◽

1986 ◽

Vol 25 (10) ◽

pp. 853-860 ◽

Cited By ~ 12

Author(s):

Kim Henrick ◽

Mary McPartlin ◽

Jill Morris

Keyword(s):

Computer Graphics ◽

Metal Cluster ◽

Cluster Compounds

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Physical properties of metal cluster compounds II: Dc-conductivity of the high-nuclearity gold cluster compound Au55(PPh3)12Cl6

Solid State Communications ◽

10.1016/0038-1098(86)90741-6 ◽

1986 ◽

Vol 60 (4) ◽

pp. 319-322 ◽

Cited By ~ 30

Author(s):

M.P.J. van Staveren ◽

H.B. Brom ◽

L.J. de Jongh ◽

G. Schmid

Keyword(s):

Physical Properties ◽

Gold Cluster ◽

Metal Cluster ◽

Dc Conductivity ◽

Cluster Compounds ◽

Cluster Compound

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Physical Properties of High-nuclearity Metal Cluster Compounds: Model Systems for Uniform-sized Metal Particles

From Simplicity to Complexity in Chemistry — and Beyond ◽

10.1007/978-3-642-49368-3_13 ◽

1996 ◽

pp. 163-169

Author(s):

L. Jos de Jongh

Keyword(s):

Physical Properties ◽

Metal Cluster ◽

Model Systems ◽

Cluster Compounds ◽

Metal Particles

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HETERONUCLEAR TRANSITION METAL CLUSTER COMPOUNDS CONTAINING ONE OR TWO GOLD ATOMS

Organometallic Syntheses ◽

10.1016/b978-0-444-42956-8.50071-2 ◽

1988 ◽

pp. 247-252 ◽

Cited By ~ 2

Author(s):

SCOTT S.D. BROWN ◽

IAN D. SALTER

Keyword(s):

Transition Metal ◽

Metal Cluster ◽

Cluster Compounds ◽

Transition Metal Cluster

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Bond-valence model for metal cluster compounds. I. Common lattice strains

Acta Crystallographica Section B Structural Science Crystal Engineering and Materials ◽

10.1107/s2052519213021271 ◽

2013 ◽

Vol 69 (5) ◽

pp. 419-425 ◽

Cited By ~ 8

Author(s):

Elena Levi ◽

Doron Aurbach ◽

Olivier Isnard

Keyword(s):

Metal Cluster ◽

Bond Valence ◽

Cluster Compounds ◽

Lattice Strains ◽

Bond Valence Model

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The heteronuclear cluster chemistry of the Group 1B metals. Part 6. Synthesis, structures, and dynamic behaviour of the bimetallic hexanuclear Group 1B metal cluster compounds [M2Ru4(µ3-H)2{µ-Ph2P(CH2)nPPh2}(CO)12](M = Cu or Ag, n= 1–6). X-Ray crystal structures of [Cu2Ru4(µ3-H)2{µ-Ph2P(CH2)nPPh2}(CO)12](n= 2, 3, or 5)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9880000757 ◽

1988 ◽

pp. 757-767 ◽

Cited By ~ 24

Author(s):

Scott S. D. Brown ◽

Ian D. Salter ◽

Loïc Toupet

Keyword(s):

Crystal Structures ◽

Dynamic Behaviour ◽

Metal Cluster ◽

Cluster Compounds ◽

Cluster Chemistry ◽

X Ray ◽

Heteronuclear Cluster

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Lattice Strains in the Ligand Framework in the Octahedral Metal Cluster Compounds as the Origin of Their Instability

Chemistry of Materials ◽

10.1021/cm103617e ◽

2011 ◽

Vol 23 (7) ◽

pp. 1901-1914 ◽

Cited By ~ 14

Author(s):

Elena Levi ◽

Doron Aurbach

Keyword(s):

Metal Cluster ◽

Cluster Compounds ◽

Lattice Strains

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ChemInform Abstract: Structural Variability in Metal Cluster Compounds

ChemInform ◽

10.1002/chin.199241300 ◽

2010 ◽

Vol 23 (41) ◽

pp. no-no

Author(s):

V. G. ALBANO ◽

D. BRAGA

Keyword(s):

Metal Cluster ◽

Cluster Compounds ◽

Structural Variability

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ChemInform Abstract: Some Aspects of Metal Cluster Compounds with Special Reference to Molybdenum and Tungsten

ChemInform ◽

10.1002/chin.199532256 ◽

2010 ◽

Vol 26 (32) ◽

pp. no-no

Author(s):

V. A. RAMAM

Keyword(s):

Special Reference ◽

Metal Cluster ◽

Cluster Compounds ◽

And Tungsten

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X-ray attenuation coefficients of high-atomic-number, hexanuclear transition metal cluster compounds: A new paradigm for radiographic contrast agents

Academic Radiology ◽

10.1016/s1076-6332(00)80475-4 ◽

2000 ◽

Vol 7 (4) ◽

pp. 254-259 ◽

Cited By ~ 19

Author(s):

Brian F. Mullan ◽

Mark T. Madsen ◽

Louis Messerle ◽

Vladimir Kolesnichenko ◽

Jason Kruger

Keyword(s):

Transition Metal ◽

Contrast Agents ◽

Atomic Number ◽

Metal Cluster ◽

Cluster Compounds ◽

New Paradigm ◽

Attenuation Coefficients ◽

X Ray ◽

Transition Metal Cluster ◽

Radiographic Contrast

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A Covalently Linked 10 Nm Gold Immunoprobe

Microscopy and Microanalysis ◽

10.1017/s1431927600019942 ◽

1999 ◽

Vol 5 (S2) ◽

pp. 1324-1325

Author(s):

Edmund Gutierrez ◽

Richard D. Powell ◽

James F. Hainfeld ◽

Peter M. Takvorian

Keyword(s):

Colloidal Gold ◽

Metal Cluster ◽

Molecular Wires ◽

Cluster Compounds ◽

Nonspecific Binding ◽

Double Labeling ◽

Tissue Sections ◽

Wide Range ◽

Covalently Linked ◽

Source Of Error

Chemically functionalized metal cluster compounds have demonstrated important advantages over colloidal gold as biological microscopy labels. They are covalently cross-linked to the targeting biomolecule, and therefore may be conjugated to a wide range of molecules which cannot be labeled with colloidal gold. The 1.4 nm Nanogold® cluster has been conjugated to peptides, lipids and oligonucleotides, some of which have been proposed as elements of novel molecular wires and novel materials. Dissociation of colloidal gold particles from the conjugate probe, a source of error in quantitative immunogold studies, is greatly reduced by covalent cross-linking. Nanogold® is an uncharged molecule, and because its surface is completely coordinated by organic ligands, nonspecific binding is greatly reduced. Nanogold® conjugates also show greatly enhanced penetration into cells and tissue sections. However, gold probes larger than Nanogold® are desirable for improved visualization in specimens with electron-dense regions or staining, or for applications such as double labeling studies with different sized gold labels, or visualizing wider antigen distributions.

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