Reaction of Allyl Halides with Diazomethane Catalysed by Copper Salts

1965 ◽  
Vol 4 (8) ◽  
pp. 691-692
Author(s):  
W. Kirmse ◽  
M. Kapps
Keyword(s):  
Copper Salts ◽  
Allyl Halides

Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

2019 ◽  
Author(s):  
Lucy van Dijk ◽  
Ruchuta Ardkhean ◽  
Mireia Sidera ◽  
Sedef Karabiyikoglu ◽  
Özlem Sari ◽  
...  
Keyword(s):  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Experimental Studies ◽  
Mechanistic Investigation ◽  
Allyl Halides

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations. <br>

scholarly journals Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Guogang Deng ◽  
Shengzu Duan ◽  
Jing Wang ◽  
Zhuo Chen ◽  
Tongqi Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Allyl Ether ◽  
Metal Catalyst ◽  
Metal Free ◽  
Allyl Ethers ◽  
Bond Forming ◽  
Allyl Halides ◽  
Synthetic Utility ◽  
Insight Into ◽  
Allyl Esters

AbstractAllylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition-metal-free allylation strategy with allyl ether electrophiles. Reaction of a host of allyl ethers with 2-azaallyl anions delivers valuable homoallylic amine derivatives (up to 92%), which are significant in the pharmaceutical industry. Interestingly, no deprotonative isomerization or cyclization of the products were observed. The potential synthetic utility and ease of operation is demonstrated by a gram scale telescoped preparation of a homoallylic amine. In addition, mechanistic studies provide insight into these C(sp3)–C(sp3) bond-forming reactions.

The Reactivity of Electrophilic Allyl Halides Towards Nucleophiles

2010 ◽  
Vol 91 (5) ◽  
pp. 430-430 ◽  
Author(s):  
R. Verhé ◽  
R. Thierie ◽  
D. Courtheyn ◽  
N. De Kimpe ◽  
L. De Buyck ◽  
...  
Keyword(s):  
Allyl Halides

Reaction of allyl halides with trichlorogermane

1960 ◽  
Vol 9 (11) ◽  
pp. 1920-1920
Author(s):  
V. F. Mironov ◽  
N. G. Dzhurinskaya ◽  
A. D. Petrov
Keyword(s):  
Allyl Halides

ChemInform Abstract: Reaction of Allyl Halides with Silyl Acetylenes.

ChemInform ◽  
2010 ◽  
Vol 25 (43) ◽  
pp. no-no
Author(s):  
M. D. STADNICHUK ◽  
E. A. ALEKSANDROVA
Keyword(s):  
Allyl Halides

scholarly journals SELECTIVE BUTYLAMINATION OF 5,8-DIHYDROXY-1,4-NAPHTHOQUINONE PROMOTED BY COPPER SALTS

1979 ◽  
Vol 8 (6) ◽  
pp. 627-630 ◽  
Author(s):  
Masaru Matsuoka ◽  
Toshio Takei ◽  
Teijiro Kitao
Keyword(s):  
Copper Salts

Aldehyde Complexes of Copper Salts

1940 ◽  
Vol 62 (5) ◽  
pp. 1272-1274 ◽  
Author(s):  
Tenney L. Davis ◽  
Walter P. Green
Keyword(s):  
Copper Salts
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