scholarly journals A Cobalt@Cucurbit[5]uril Complex as a Highly Efficient Supramolecular Catalyst for Electrochemical and Photoelectrochemical Water Splitting

2020 ◽  
Author(s):  
Fusheng Li ◽  
Hao Yang ◽  
Qiming Zhuo ◽  
Dinghua Zhou ◽  
Xiujuan Wu ◽  
...  
Keyword(s):  
Water Splitting ◽  
Photoelectrochemical Water Splitting ◽  
Highly Efficient

One-Dimensional TiO2@GaON Core-Shell Nanowires with Controlled Shell Thickness from Atomic Layer Deposition for Stable and Efficient Photoelectrochemical Water Splitting

2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Band Gap ◽  
Water Splitting ◽  
Atomic Layer ◽  
Photoelectrochemical Water Splitting ◽  
Core Shell ◽  
Photoelectrochemical Performance ◽  
Highly Efficient ◽  
Layer Deposition ◽  
Shell Nanowires

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>

Defective Fe3+ self-doped spinel ZnFe2O4 with oxygen vacancies for highly efficient photoelectrochemical water splitting

2019 ◽  
Vol 48 (31) ◽  
pp. 11934-11940 ◽  
Author(s):  
Jianmin Wang ◽  
Yunan Wang ◽  
Xinchao Xv ◽  
Yan Chen ◽  
Xi Yang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Vacancies ◽  
Photoelectrochemical Water Splitting ◽  
Photoelectrochemical Performance ◽  
Highly Efficient

Defective Fe3+ self-doped spinel ZnFe2O4 with abundant oxygen vacancies exhibits largely enhanced photoelectrochemical performance.

TiO2/graphene/NiFe-layered double hydroxide nanorod array photoanodes for efficient photoelectrochemical water splitting

2016 ◽  
Vol 9 (8) ◽  
pp. 2633-2643 ◽  
Author(s):  
Fanyu Ning ◽  
Mingfei Shao ◽  
Simin Xu ◽  
Yi Fu ◽  
Ruikang Zhang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Layered Double Hydroxide ◽  
Water Oxidation ◽  
Charge Separation ◽  
Nanorod Array ◽  
Photoelectrochemical Water Splitting ◽  
Nanorod Arrays ◽  
Highly Efficient ◽  
Oxidation Efficiency ◽  
Double Hydroxide

TiO2/graphene/NiFe-layered double hydroxide nanorod arrays were fabricated as highly efficient photoanodes for photoelectrochemical water splitting with simultaneously enhanced charge separation and water oxidation efficiency.

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