scholarly journals Cross‐Linking between Sodalite Nanoparticles and Graphene Oxide in Composite Membranes to Trigger High Gas Permeance, Selectivity, and Stability in Hydrogen Separation

2020 ◽  
Vol 132 (15) ◽  
pp. 6343-6347
Author(s):  
Hailing Guo ◽  
Guodong Kong ◽  
Ge Yang ◽  
Jia Pang ◽  
Zixi Kang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Composite Membranes ◽  
Hydrogen Separation ◽  
Cross Linking

scholarly journals Chemically Cross-Linked Graphene Oxide as a Selective Layer on Electrospun Polyvinyl Alcohol Nanofiber Membrane for Nanofiltration Application

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2867
Author(s):  
Myoung Jun Park ◽  
Grace M. Nisola ◽  
Dong Han Seo ◽  
Chen Wang ◽  
Sherub Phuntsho ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Polyvinyl Alcohol ◽  
Self Assembly ◽  
Water Flux ◽  
Composite Membranes ◽  
Cross Linking ◽  
Support Surface ◽  
Eosin Y ◽  
Selective Layer ◽  
Assembly Technique

Graphene oxide (GO) nanosheets were utilized as a selective layer on a highly porous polyvinyl alcohol (PVA) nanofiber support via a pressure-assisted self-assembly technique to synthesize composite nanofiltration membranes. The GO layer was rendered stable by cross-linking the nanosheets (GO-to-GO) and by linking them onto the support surface (GO-to-PVA) using glutaraldehyde (GA). The amounts of GO and GA deposited on the PVA substrate were varied to determine the optimum nanofiltration membrane both in terms of water flux and salt rejection performances. The successful GA cross-linking of GO interlayers and GO-PVA via acetalization was confirmed by FTIR and XPS analyses, which corroborated with other characterization results from contact angle and zeta potential measurements. Morphologies of the most effective membrane (CGOPVA-50) featured a defect-free GA cross-linked GO layer with a thickness of ~67 nm. The best solute rejections of the CGOPVA-50 membrane were 91.01% for Na2SO4 (20 mM), 98.12% for Eosin Y (10 mg/L), 76.92% for Methylene blue (10 mg/L), and 49.62% for NaCl (20 mM). These findings may provide one of the promising approaches in synthesizing mechanically stable GO-based thin-film composite membranes that are effective for solute separation via nanofiltration.

scholarly journals Cross-Linking With Diamine Monomers to Prepare Graphene Oxide Composite Membranes With Varying D-Spacing for Enhanced Desalination Properties

2021 ◽  
Vol 9 ◽  
Author(s):  
Hong Ju ◽  
Jinzhuo Duan ◽  
Haitong Lu ◽  
Weihui Xu
Keyword(s):  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Water Flux ◽  
Covalent Bond ◽  
Composite Membranes ◽  
Rejection Rate ◽  
High Water ◽  
Cross Linking ◽  
Separation Performance ◽  
X Ray

As a new type of membrane material, graphene oxide (GO) can easily form sub-nanometer interlayer channels, which can effectively screen salt ions. The composite membrane and structure with a high water flux and good ion rejection rate were compared by the cross-linking of GO with three different diamine monomers: ethylenediamine (EDA), urea (UR), and p-phenylenediamine (PPD). X-ray photoelectron spectroscopy (XPS) results showed that unmodified GO mainly comprises π-π interactions and hydrogen bonds, but after crosslinking with diamine, both GO and mixed cellulose (MCE) membranes are chemically bonded to the diamine. The GO-UR/MCE membrane achieved a water flux similar to the original GO membrane, while the water flux of GO-PPD/MCE and GO-EDA/MCE dropped. X-ray diffraction results demonstrated that the covalent bond between GO and diamine can effectively inhibit the extension of d-spacing during the transition between dry and wet states. The separation performance of the GO-UR/MCE membrane was the best. GO-PPD/MCE had the largest contact angle and the worst hydrophilicity, but its water flux was still greater than GO-EDA/MCE. This result indicated that the introduction of different functional groups during the diamine monomer cross-linking of GO caused some changes in the performance structure of the membrane.

One-step enhancement of solvent transport, stability and photocatalytic properties of graphene oxide/polyimide membranes with multifunctional cross-linkers

2019 ◽  
Vol 7 (7) ◽  
pp. 3170-3178 ◽  
Author(s):  
Mei-Ling Liu ◽  
Jia-Lin Guo ◽  
Susilo Japip ◽  
Tian-Zhi Jia ◽  
Dan-Dan Shao ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Photocatalytic Performance ◽  
Composite Membranes ◽  
Photocatalytic Properties ◽  
Cross Linking ◽  
One Step ◽  
The Stability ◽  
Solvent Transport ◽  
Polyimide Membranes

Improving the stability and photocatalytic performance of GO/PI composite membranes by a one-step cross-linking method.

scholarly journals Hyperbranched polyamide modified graphene oxide-reinforced polyurethane nanocomposites with enhanced mechanical properties

RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14484-14494
Author(s):  
Yahao Liu ◽  
Jian Zheng ◽  
Xiao Zhang ◽  
Yongqiang Du ◽  
Guibo Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
High Performance ◽  
Cross Linking ◽  
Elongation At Break ◽  
Modified Graphene Oxide ◽  
High Performance Composite ◽  
Modified Graphene ◽  
Polyurethane Nanocomposites ◽  
Hyperbranched Polyamide

We successfully modified graphene oxide with amino-terminated hyperbranched polyamide (HGO), and obtained a high-performance composite with enhanced strength and elongation at break via cross-linking hydroxyl-terminated polybutadiene chains with HGO.

Polyvinylamine/graphene oxide/PANI@CNTs mixed matrix composite membranes with enhanced CO2/N2 separation performance

2019 ◽  
Vol 589 ◽  
pp. 117246 ◽  
Author(s):  
Yonghong Wang ◽  
Long Li ◽  
Xinru Zhang ◽  
Jinping Li ◽  
Chengcen Liu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Matrix Composite ◽  
Composite Membranes ◽  
Separation Performance ◽  
Mixed Matrix

Fabrication of defect-free Pd/α-Al2O3 composite membranes for hydrogen separation

1999 ◽  
Vol 350 (1-2) ◽  
pp. 106-112 ◽  
Author(s):  
Anwu Li ◽  
Weiqiang Liang ◽  
Ronald Hughes
Keyword(s):  
Composite Membranes ◽  
Hydrogen Separation ◽  
Al2o3 Composite ◽  
Α Al2o3
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