A Mechanistic Analysis of the Palladium‐Catalyzed Formation of Branched Allylic Amines Reveals the Origin of the Regio‐ and Enantioselectivity through a Unique Inner‐Sphere Pathway

2019 ◽  
Vol 131 (41) ◽  
pp. 14836-14844 ◽  
Author(s):  
Lingfei Hu ◽  
Aijie Cai ◽  
Zhenzhen Wu ◽  
Arjan W. Kleij ◽  
Genping Huang
Keyword(s):  
Allylic Amines ◽  
Mechanistic Analysis ◽  
Inner Sphere ◽  
Palladium Catalyzed

An efficient, palladium-catalyzed route to protected allylic amines

1988 ◽  
Vol 53 (16) ◽  
pp. 3845-3849 ◽  
Author(s):  
Richard D. Connell ◽  
Tobias Rein ◽  
Bjoern Aakermark ◽  
Paul Helquist
Keyword(s):  
Allylic Amines ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons

2016 ◽  
Vol 138 (43) ◽  
pp. 14194-14197 ◽  
Author(s):  
Aijie Cai ◽  
Wusheng Guo ◽  
Luis Martínez-Rodríguez ◽  
Arjan W. Kleij
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Amines ◽  
Palladium Catalyzed

Regioselective Synthesis of Optically Active Trifluoromethyl Group Substituted Allylic Amines by Palladium-Catalyzed Allylic Amination

Synlett ◽  
2010 ◽  
Vol 2010 (19) ◽  
pp. 2887-2890 ◽  
Author(s):  
Motoi Kawatsura ◽  
Toshiyuki Itoh ◽  
Takuya Hirakawa ◽  
Kazunori Ikeda ◽  
Hiroshi Ogasa
Keyword(s):  
Optically Active ◽  
Regioselective Synthesis ◽  
Trifluoromethyl Group ◽  
Allylic Amines ◽  
Allylic Amination ◽  
Palladium Catalyzed

Palladium-catalyzed coupling of organic halides and tertiary allylic amines

1993 ◽  
Vol 34 (10) ◽  
pp. 1643-1646 ◽  
Author(s):  
Lucio Filippini ◽  
Marilena Gusmeroli ◽  
Raul Riva
Keyword(s):  
Allylic Amines ◽  
Organic Halides ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Coupling of Organic Halides and Tertiary Allylic Amines.

ChemInform ◽  
2010 ◽  
Vol 24 (29) ◽  
pp. no-no
Author(s):  
L. FILIPPINI ◽  
M. GUSMEROLI ◽  
R. RIVA
Keyword(s):  
Allylic Amines ◽  
Organic Halides ◽  
Palladium Catalyzed
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