A Metal–Organic Supramolecular Box as a Universal Reservoir of UV, WL, and NIR Light for Long‐Persistent Luminescence

2019 ◽  
Vol 131 (11) ◽  
pp. 3519-3523 ◽  
Author(s):  
Zheng Wang ◽  
Cheng‐Yi Zhu ◽  
Shao‐Yun Yin ◽  
Zhang‐Wen Wei ◽  
Jian‐Hua Zhang ◽  
...  
Keyword(s):  
Persistent Luminescence ◽  
Nir Light ◽  
Metal Organic

A Metal–Organic Supramolecular Box as a Universal Reservoir of UV, WL, and NIR Light for Long‐Persistent Luminescence

2019 ◽  
Vol 58 (11) ◽  
pp. 3481-3485 ◽  
Author(s):  
Zheng Wang ◽  
Cheng‐Yi Zhu ◽  
Shao‐Yun Yin ◽  
Zhang‐Wen Wei ◽  
Jian‐Hua Zhang ◽  
...  
Keyword(s):  
Persistent Luminescence ◽  
Nir Light ◽  
Metal Organic

scholarly journals MOFs-based nanoagent enables dual mitochondrial damage in synergistic antitumor therapy via oxidative stress and calcium overload

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Weier Bao ◽  
Ming Liu ◽  
Jiaqi Meng ◽  
Siyuan Liu ◽  
Shuang Wang ◽  
...  
Keyword(s):  
Oxidative Stress ◽  
Near Infrared ◽  
Calcium Influx ◽  
Calcium Overload ◽  
Tumor Xenograft ◽  
Great Promise ◽  
Antitumor Therapy ◽  
Nir Light ◽  
Metal Organic

AbstractTargeting subcellular organelle with multilevel damage has shown great promise for antitumor therapy. Here, we report a core-shell type of nanoagent with iron (III) carboxylate metal-organic frameworks (MOFs) as shell while upconversion nanoparticles (UCNPs) as core, which enables near-infrared (NIR) light-triggered synergistically reinforced oxidative stress and calcium overload to mitochondria. The folate decoration on MOFs shells enables efficient cellular uptake of nanoagents. Based on the upconversion ability of UCNPs, NIR light mediates Fe3+-to-Fe2+ reduction and simultaneously activates the photoacid generator (pHP) encapsulated in MOFs cavities, which enables release of free Fe2+ and acidification of intracellular microenvironment, respectively. The overexpressed H2O2 in mitochondria, highly reactive Fe2+ and acidic milieu synergistically reinforce Fenton reactions for producing lethal hydroxyl radicals (•OH) while plasma photoacidification inducing calcium influx, leading to mitochondria calcium overload. The dual-mitochondria-damage-based therapeutic potency of the nanoagent has been unequivocally confirmed in cell- and patient-derived tumor xenograft models in vivo.

A long persistent phosphorescent metal–organic framework for multi-level sensing of oxygen

2020 ◽  
Vol 8 (29) ◽  
pp. 9916-9922 ◽  
Author(s):  
Cheng-Yi Zhu ◽  
Zheng Wang ◽  
Jun-Ting Mo ◽  
Ya-Nan Fan ◽  
Mei Pan
Keyword(s):  
Metal Organic Framework ◽  
Persistent Luminescence ◽  
Oxygen Detection ◽  
Metal Organic ◽  
Multi Level ◽  
Organic Framework

A novel metal–organic framework (MOF) with long persistent luminescence (LPL) for multilevel oxygen detection is proposed.

Enhanced Long Persistent Luminescence by Multifold Interpenetration in Metal–Organic Frameworks

2020 ◽  
Vol 26 (33) ◽  
pp. 7458-7462 ◽  
Author(s):  
Zheng Wang ◽  
Cheng‐Yi Zhu ◽  
Peng‐Yan Fu ◽  
Jun‐Ting Mo ◽  
Jia Ruan ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Persistent Luminescence ◽  
Metal Organic

Infrared-photostimulable and long-persistent ultraviolet-emitting phosphor LiLuGeO4:Bi3+,Yb3+ for biophotonic applications

2021 ◽  
Author(s):  
Hao Cai ◽  
Zhen Song ◽  
Quanlin Liu
Keyword(s):  
Biological Tissue ◽  
Persistent Luminescence ◽  
Nir Light

A long-persistent ultraviolet-emitting phosphor LiLuGeO4:Bi3+,Yb3+ is synthesized. This phosphor exhibits simulated in vivo photostimulated persistent luminescence after a longtime decay by using in vitro NIR light penetrating biological tissue.

Broadband near-infrared emission of La3Ga5GeO14:Tb3+,Cr3+ phosphors: energy transfer, persistent luminescence and application in NIR light-emitting diodes

2020 ◽  
Vol 8 (34) ◽  
pp. 11760-11770
Author(s):  
Biao Bai ◽  
Peipei Dang ◽  
Zhongli Zhu ◽  
Hongzhou Lian ◽  
Jun Lin
Keyword(s):  
Energy Transfer ◽  
Near Infrared ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Infrared Emission ◽  
Persistent Luminescence ◽  
Light Emitting ◽  
Nir Light ◽  
Near Infrared Emission

A broadband near-infrared La3Ga5GeO14:Tb3+,Cr3+ phosphor with high efficiency was achieved via design of energy transfer for NIR LEDs.

Lanthanide-based near-infrared emitting metal–organic frameworks with tunable excitation wavelengths and high quantum yields

2018 ◽  
Vol 54 (50) ◽  
pp. 6816-6819 ◽  
Author(s):  
Tu N. Nguyen ◽  
Gloria Capano ◽  
Andrzej Gładysiak ◽  
Fatmah Mish Ebrahim ◽  
Svetlana V. Eliseeva ◽  
...  
Keyword(s):  
Visible Light ◽  
Light Absorption ◽  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Quantum Yields ◽  
Visible Light Absorption ◽  
High Quantum ◽  
Nir Light ◽  
Metal Organic

The introduction of –NH2 group in SION-100 allows the visible light absorption, and both SION-100 and SION-100-NH2 luminesce NIR light with long lifetimes and high quantum yields.

Breathing-Ignited Long Persistent Luminescence in a Resilient Metal–Organic Framework

2019 ◽  
Vol 32 (2) ◽  
pp. 841-848 ◽  
Author(s):  
Zheng Wang ◽  
Cheng-Yi Zhu ◽  
Zhang-Wen Wei ◽  
Ya-Nan Fan ◽  
Mei Pan
Keyword(s):  
Metal Organic Framework ◽  
Persistent Luminescence ◽  
Metal Organic ◽  
Organic Framework

Transformable upconversion metal-organic frameworks for near-infrared light-programmed chemotherapy

2021 ◽  
Author(s):  
Fang Wang ◽  
Zhen Li ◽  
Xiaobo Zhang ◽  
Rengan Luo ◽  
Hanlin Hou ◽  
...  
Keyword(s):  
Delivery System ◽  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Resonance Energy ◽  
Infrared Light ◽  
Near Infrared Light ◽  
Nir Light ◽  
Energy Transfers ◽  
Metal Organic ◽  
Förster Resonance

A transformable upconversion MOF composing UCNP core and azobenzene-based MOF shell is designed for NIR light-modulated chemotherapy. The dual Förster resonance energy transfers (FRET) involved in this delivery system trigger...

Electron microscope characterization of MOCVD-grown gap layers on Si

1986 ◽  
Vol 44 ◽  
pp. 724-725
Author(s):  
K.M. Jones ◽  
M.M. Al-Jassim ◽  
J.M. Olson
Keyword(s):  
Atmospheric Pressure ◽  
Vapour Deposition ◽  
Chemical Vapour ◽  
Organic Chemical ◽  
Lattice Match ◽  
Si Substrates ◽  
Metal Organic ◽  
Good Lattice ◽  
Antiphase Domains

The epitaxial growth of III-V semiconductors on Si for integrated optoelectronic applications is currently of great interest. GaP, with a lattice constant close to that of Si, is an attractive buffer between Si and, for example, GaAsP. In spite of the good lattice match, the growth of device quality GaP on Si is not without difficulty. The formation of antiphase domains, the difficulty in cleaning the Si substrates prior to growth, and the poor layer morphology are some of the problems encountered. In this work, the structural perfection of GaP layers was investigated as a function of several process variables including growth rate and temperature, and Si substrate orientation. The GaP layers were grown in an atmospheric pressure metal organic chemical vapour deposition (MOCVD) system using trimethylgallium and phosphine in H2. The Si substrates orientations used were (100), 2° off (100) towards (110), (111) and (211).

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