Divergent Reactivity of Stannane and Silane in the Trifluoromethylation of PdII: Cyclic Transition State versus Difluorocarbene Release

Maoping Pu; Italo A. Sanhueza; Erdem Senol; Franziska Schoenebeck

doi:10.1002/ange.201808229

Divergent Reactivity of Stannane and Silane in the Trifluoromethylation of PdII: Cyclic Transition State versus Difluorocarbene Release

Angewandte Chemie ◽

10.1002/ange.201808229 ◽

2018 ◽

Vol 130 (46) ◽

pp. 15301-15305 ◽

Cited By ~ 2

Author(s):

Maoping Pu ◽

Italo A. Sanhueza ◽

Erdem Senol ◽

Franziska Schoenebeck

Keyword(s):

Transition State ◽

Cyclic Transition ◽

Cyclic Transition State

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ChemInform Abstract: REMOTE PHOTOCYCLIZATION OF (DIBENZYLAMINO)ETHYL BENZOYLACETATE. INTRAMOLECULAR HYDROGEN ABSTRACTION THROUGH A TEN-MEMBERED CYCLIC TRANSITION STATE

Chemischer Informationsdienst ◽

10.1002/chin.198527261 ◽

1985 ◽

Vol 16 (27) ◽

Author(s):

T. HASEGAWA ◽

K. MIYATA ◽

T. OGAWA ◽

N. YOSHIHARA ◽

M. YOSHIOKA

Keyword(s):

Transition State ◽

Hydrogen Abstraction ◽

Cyclic Transition ◽

Cyclic Transition State ◽

Intramolecular Hydrogen

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A Bifunctional B,N‐Based Asymmetric Catalytic Nitrostyrene‐ Michael Addition Acting through a 10‐Membered Ring Cyclic Transition State

Helvetica Chimica Acta ◽

10.1002/hlca.202100199 ◽

2021 ◽

Author(s):

Yihao Du ◽

Ozlem Sari ◽

Safiye S. Erdem ◽

Andrew Whiting

Keyword(s):

Transition State ◽

Michael Addition ◽

Membered Ring ◽

Cyclic Transition ◽

Asymmetric Catalytic ◽

Cyclic Transition State

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Molecular photochemistry. XXXVI. Photochemistry of some .alpha.-oxopropiophenones. Evidence for an unusual cyclic transition state for hydrogen abstraction

Journal of the American Chemical Society ◽

10.1021/ja00728a040 ◽

1970 ◽

Vol 92 (25) ◽

pp. 7467-7470 ◽

Cited By ~ 14

Author(s):

Nicholas J. Turro ◽

Ta-Jyh. Lee

Keyword(s):

Transition State ◽

Hydrogen Abstraction ◽

Cyclic Transition ◽

Cyclic Transition State

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Mass Spectrometry in Structural and Stereochemical Problems. LXXXV.1The Nature of the Cyclic Transition State in Hydrogen Rearrangements of Aliphatic Amines2,3

Journal of the American Chemical Society ◽

10.1021/ja00952a040 ◽

1965 ◽

Vol 87 (24) ◽

pp. 5752-5756 ◽

Cited By ~ 51

Author(s):

Carl Djerassi ◽

Catherine Fenselau

Keyword(s):

Mass Spectrometry ◽

Transition State ◽

Cyclic Transition ◽

Cyclic Transition State

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The asymmetric Michael reaction using chiral imines under neutral conditions: Stereochemical evidences in support of a cyclic transition state

Tetrahedron Letters ◽

10.1016/0040-4039(94)88365-3 ◽

1994 ◽

Vol 35 (52) ◽

pp. 9705-9708 ◽

Cited By ~ 14

Author(s):

Lydia Ambroise ◽

Didier Desmaële ◽

Jacqueline Mahuteau ◽

Jean d'Angelo

Keyword(s):

Transition State ◽

Michael Reaction ◽

Cyclic Transition ◽

Cyclic Transition State ◽

Asymmetric Michael Reaction ◽

Chiral Imines ◽

Neutral Conditions

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ChemInform Abstract: A Cyclic Transition State for the Darzen Reaction.

ChemInform ◽

10.1002/chin.199705054 ◽

2010 ◽

Vol 28 (5) ◽

pp. no-no

Author(s):

A. YLINIEMELAE ◽

G. BRUNOW ◽

J. FLUEGGE ◽

O. TELEMAN

Keyword(s):

Transition State ◽

Cyclic Transition ◽

Cyclic Transition State

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Mechanism of the reactions of substituted anilines with phenyl 2,4,6-trinitrophenyl ether in benzene: evidence for a cyclic transition state involving an eight-membered ring

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29820001357 ◽

1982 ◽

pp. 1357 ◽

Cited By ~ 14

Author(s):

Olayinka Banjoko ◽

Chike Ezeani

Keyword(s):

Transition State ◽

Membered Ring ◽

Substituted Anilines ◽

Cyclic Transition ◽

Cyclic Transition State

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ChemInform Abstract: SEVEN-MEMBERED CYCLIC TRANSITION STATE IN THE ALKOXY-RADICAL INDUCED INTRAMOLECULAR HYDROGEN ABSTRACTION OF 26-HYDROXYFUROSTANS

Chemischer Informationsdienst ◽

10.1002/chin.198412321 ◽

1984 ◽

Vol 15 (12) ◽

Author(s):

C. G. FRANCISCO ◽

R. FREIRE ◽

R. HERNANDEZ ◽

M. C. MEDINA ◽

E. SUAREZ

Keyword(s):

Transition State ◽

Hydrogen Abstraction ◽

Alkoxy Radical ◽

Cyclic Transition ◽

Cyclic Transition State ◽

Intramolecular Hydrogen

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Photochemistry of o-benzyloxyphenylglyoxylates. A case of favored intramolecular hydrogen abstraction via a seven-membered cyclic transition state

Journal of the American Chemical Society ◽

10.1021/ja00726a033 ◽

1970 ◽

Vol 92 (23) ◽

pp. 6927-6931 ◽

Cited By ~ 22

Author(s):

Socrates P. Pappas ◽

James E. Alexander ◽

Robert D. Zehr

Keyword(s):

Transition State ◽

Hydrogen Abstraction ◽

Cyclic Transition ◽

Cyclic Transition State ◽

Intramolecular Hydrogen

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Cyclic transition state in the acid catalyzed intramolecular allylstannane-aldehyde condensation

Tetrahedron Letters ◽

10.1016/s0040-4039(00)91783-0 ◽

1993 ◽

Vol 34 (8) ◽

pp. 1313-1316 ◽

Cited By ~ 33

Author(s):

Vladimir Gevorgyan ◽

Isao Kadota ◽

Yoshinori Yamamoto

Keyword(s):

Transition State ◽

Cyclic Transition ◽

Cyclic Transition State ◽

Acid Catalyzed

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