scholarly journals Palladium-Catalyzed Enantioselective Arylation of Racemic Ketones to Form Bridged Bicycles via Dynamic Kinetic Resolution

2018 ◽  
Vol 130 (26) ◽  
pp. 7799-7803 ◽  
Author(s):  
Xiaolei Huang ◽  
William Ray Jun Jie Oh ◽  
Jianrong Steve Zhou
Keyword(s):  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Palladium Catalyzed

Mechanism and origins of stereo- and enantioselectivities of palladium-catalyzed hydroamination of racemic internal allenes via dynamic kinetic resolution: a computational study

2020 ◽  
Vol 7 (12) ◽  
pp. 1502-1511 ◽  
Author(s):  
Zhenzhen Wu ◽  
Mei Zhang ◽  
Yu Shi ◽  
Genping Huang
Keyword(s):  
Dft Calculations ◽  
Kinetic Resolution ◽  
Computational Study ◽  
Dynamic Kinetic Resolution ◽  
Palladium Catalyzed

DFT calculations were performed to investigate the Pd-catalyzed hydroamination of racemic internal allenes with pyrazoles.

Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions

2020 ◽  
Vol 56 (43) ◽  
pp. 5815-5818 ◽  
Author(s):  
Xiang Li ◽  
Zi-Biao Zhao ◽  
Mu-Wang Chen ◽  
Bo Wu ◽  
Han Wang ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
Cyclic Ketones ◽  
Palladium Catalyzed ◽  
Acidic Conditions

The first efficient palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones has been described through dynamic kinetic resolution under acidic conditions, providing a facile access to chiral trans cycloalkanols.

Synthesis of chiral sultams with two adjacent stereocenters via palladium-catalyzed dynamic kinetic resolution

2018 ◽  
Vol 5 (7) ◽  
pp. 1113-1117 ◽  
Author(s):  
Bo Song ◽  
Mu-Wang Chen ◽  
Yong-Gui Zhou
Keyword(s):  
Reductive Amination ◽  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Stereogenic Centers ◽  
Palladium Catalyzed

A palladium-catalyzed intramolecular asymmetric reductive amination of racemic α-branched ketones bearing the poorly nucleophilic sulfonamides has been successfully developed through dynamic kinetic resolution, providing chiral δ-sultams with two contiguous stereogenic centers.

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