Opposing Phase-Segregation and Hydrogen-Bonding Forces in Supramolecular Polymers

2017 ◽  
Vol 129 (42) ◽  
pp. 13196-13200 ◽  
Author(s):  
Senbin Chen ◽  
Tingzi Yan ◽  
Matthias Fischer ◽  
Anton Mordvinkin ◽  
Kay Saalwächter ◽  
...  
2017 ◽  
Vol 56 (42) ◽  
pp. 13016-13020 ◽  
Author(s):  
Senbin Chen ◽  
Tingzi Yan ◽  
Matthias Fischer ◽  
Anton Mordvinkin ◽  
Kay Saalwächter ◽  
...  

2005 ◽  
Vol 127 (51) ◽  
pp. 18202-18211 ◽  
Author(s):  
Sona Sivakova ◽  
David A. Bohnsack ◽  
Michael E. Mackay ◽  
Phiriyatorn Suwanmala ◽  
Stuart J. Rowan

2020 ◽  
Author(s):  
Shuaiyuan Han ◽  
Sandrine Pensec ◽  
Cédric Lorthioir ◽  
Jacques Jestin ◽  
Jean-Michel Guigner ◽  
...  

Janus cylinders are one-dimensional colloids that have two faces with different compositions and functionalities and are useful as building blocks for advanced functional materials. Such anisotropic objects are difficult to prepare with nanometric dimensions. Here we describe a robust and versatile strategy to form micrometer long Janus nanorods with diameters in the 10-nanometer range, by self-assembly in water of end-functionalized polymers. For the first time, the Janus topology is not a result of the phase segregation of incompatible polymer arms, but is driven by the interactions between unsymmetrical and complementary hydrogen bonded stickers. It is therefore independent of the actual polymers used and works even for compatible polymers. To illustrate their applicative potential, we show that these Janus nanorods can efficiently stabilize oil-in-water emulsions.


2020 ◽  
Vol 11 (39) ◽  
pp. 6288-6294
Author(s):  
Lei Tao ◽  
Zhi-Wang Luo ◽  
Kai Lan ◽  
Ping Wang ◽  
Yan Guan ◽  
...  

Stimuli-responsive luminescent supramolecular polymers were synthesized via hydrogen bonding, which could be further used to build controllable, rewritable paper.


2020 ◽  
Author(s):  
Yufeng Huo ◽  
Zhenfeng He ◽  
Chao Wang ◽  
Lei Zhang ◽  
Qianyu Xuan ◽  
...  

Supramolecular polymers combine the properties of traditional polymers and supramolecules. They are normally formed by the self-assembled polymerization driven via noncovalent interactions (such as hydrogen bonding, π-π stacking, metal coordination,...


2013 ◽  
Vol 46 (24) ◽  
pp. 9634-9641 ◽  
Author(s):  
Adam Gooch ◽  
Natasha S. Murphy ◽  
Neil H. Thomson ◽  
Andrew J. Wilson

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