Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms

2017 ◽  
Vol 129 (17) ◽  
pp. 4790-4796 ◽  
Author(s):  
Liangbing Wang ◽  
Hongliang Li ◽  
Wenbo Zhang ◽  
Xiao Zhao ◽  
Jianxiang Qiu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ammonia Borane ◽  
Rhodium Catalysts ◽  
Occupied State

Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms

2017 ◽  
Vol 56 (17) ◽  
pp. 4712-4718 ◽  
Author(s):  
Liangbing Wang ◽  
Hongliang Li ◽  
Wenbo Zhang ◽  
Xiao Zhao ◽  
Jianxiang Qiu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ammonia Borane ◽  
Rhodium Catalysts ◽  
Occupied State

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Ultrahigh Catalytic Activity of l -Proline-Functionalized Rh Nanoparticles for Methanolysis of Ammonia Borane

ChemSusChem ◽  
2018 ◽  
Vol 12 (2) ◽  
pp. 535-541 ◽  
Author(s):  
Wenxiu Luo ◽  
Wei Cheng ◽  
Min Hu ◽  
Qi Wang ◽  
Xia Cheng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ammonia Borane

Non-noble bimetallic CuCo nanoparticles encapsulated in the pores of metal–organic frameworks: synergetic catalysis in the hydrolysis of ammonia borane for hydrogen generation

2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Alloy Nanoparticles ◽  
Metal Organic ◽  
Hydrolysis Of

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.

Morphology-dependent catalytic activity of plasmonic MoO3−x for hydrolytic dehydrogenation of ammonia borane

2017 ◽  
Vol 10 (06) ◽  
pp. 1750079 ◽  
Author(s):  
Jie Gong ◽  
Zhixue Li ◽  
Ting Zhang ◽  
Runze Chen ◽  
Xiaoying Zheng ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Catalytic Activity ◽  
Solvothermal Method ◽  
Visible Region ◽  
Volume Ratio ◽  
Ammonia Borane ◽  
Distilled Water ◽  
Facile Solvothermal Method ◽  
Solvent Volume ◽  
Catalytic Performances

Series of plasmonic MoO[Formula: see text] particles have been prepared by a facile solvothermal method to produce hydrogen via hydrolytic dehydrogenation of ammonia borane. Interestingly, the as-prepared MoO[Formula: see text] particles present various morphologies, i.e. flower, schistose and nanorod by simply tuning the reaction temperature and solvent volume ratio of distilled water and acetic acid. More importantly, these MoO[Formula: see text] particles with different morphologies exhibit various catalytic performances of NH3BH3 under the irradiation of visible light. Particularly, the flower-like MoO[Formula: see text] microstructure possesses the best catalytic activity for hydrogen production probably owing to the relatively large surface area and strong LSPR in the visible region.

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