Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy

2015 ◽  
Vol 128 (6) ◽  
pp. 2226-2230 ◽  
Author(s):  
Jia Feng ◽  
Bin Li ◽  
Yun He ◽  
Zhenhua Gu
Keyword(s):  
Palladium Catalysis ◽  
Enantioselective Synthesis

scholarly journals Traversing Steric Limitations by Cooperative Lewis Base/Palladium Catalysis: An Enantioselective Synthesis of α-Branched Esters Using 2-Substituted Allyl Electrophiles

2018 ◽  
Vol 57 (26) ◽  
pp. 7800-7803 ◽  
Author(s):  
Kevin J. Schwarz ◽  
Colin M. Pearson ◽  
Gabriel A. Cintron-Rosado ◽  
Peng Liu ◽  
Thomas N. Snaddon
Keyword(s):  
Palladium Catalysis ◽  
Enantioselective Synthesis ◽  
Lewis Base

scholarly journals An enantioselective synthesis of α-alkylated pyrroles via cooperative isothiourea/palladium catalysis

2019 ◽  
Vol 17 (7) ◽  
pp. 1787-1790 ◽  
Author(s):  
W. Rush Scaggs ◽  
Toya D. Scaggs ◽  
Thomas N. Snaddon
Keyword(s):  
Acetic Acid ◽  
Palladium Catalysis ◽  
Enantioselective Synthesis ◽  
Lewis Base ◽  
Acetic Acid Esters ◽  
Acid Esters

Herein we describe the direct enantioselective Lewis base/Pd catalysed α-allylation of pyrrole acetic acid esters.

scholarly journals Traversing Steric Limitations by Cooperative Lewis Base/Palladium Catalysis: An Enantioselective Synthesis of α-Branched Esters Using 2-Substituted Allyl Electrophiles

2018 ◽  
Vol 130 (26) ◽  
pp. 7926-7929 ◽  
Author(s):  
Kevin J. Schwarz ◽  
Colin M. Pearson ◽  
Gabriel A. Cintron-Rosado ◽  
Peng Liu ◽  
Thomas N. Snaddon
Keyword(s):  
Palladium Catalysis ◽  
Enantioselective Synthesis ◽  
Lewis Base

Catalytic enantioselective synthesis of indolizino[8,7-b]indole alkaloid derivatives based on the tandem reaction of tertiary enamides

2021 ◽  
Author(s):  
Xin-Ming Xu ◽  
Ming Xie ◽  
Jiazhu Li ◽  
Mei-Xiang Wang
Keyword(s):  
Indole Alkaloid ◽  
Enantioselective Synthesis ◽  
High Yield ◽  
Tandem Reaction ◽  
Indole Derivatives

An exquisite Pybox/Cu(OTf)2-catalyzed asymmetric tandem reaction of tertiary enamides was developed, which enabled the expeditious synthesis of indolizino[8,7-b]indole derivatives in high yield, excellent enantioselectivity and diastereoselectivity.

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