Reductive Catenation of Phosphine Antimony Complexes

2015 ◽  
Vol 127 (27) ◽  
pp. 7939-7943 ◽  
Author(s):  
Saurabh S. Chitnis ◽  
Neil Burford ◽  
Jan J. Weigand ◽  
Robert McDonald
Keyword(s):  
Antimony Complexes

scholarly journals Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction

2017 ◽  
Vol 56 (31) ◽  
pp. 9111-9115 ◽  
Author(s):  
Jianbing Jiang ◽  
Kelly L. Materna ◽  
Svante Hedström ◽  
Ke R. Yang ◽  
Robert H. Crabtree ◽  
...  
Keyword(s):  
Main Group ◽  
Group Element ◽  
Proton Reduction ◽  
Main Group Element ◽  
Antimony Complexes

Nuclear Quadrupole Resonance Studies of Chelated Antimony Complexes. Part III. The Carboxylates: RCO2SbCl4

1986 ◽  
Vol 41 (1-2) ◽  
pp. 179-185
Author(s):  
Claudine Gerard-Dion ◽  
Joyce Rupp-Bensadon ◽  
Edwin A. C. Lucken
Keyword(s):  
Phase Change ◽  
Nuclear Quadrupole Resonance ◽  
Chlorine Atoms ◽  
Resonance Frequencies ◽  
Quadrupole Resonance ◽  
Antimony Complexes ◽  
Quantitative Basis ◽  
Nuclear Quadrupole ◽  
The Difference

The 35Cl, 121Sb and 123Sb resonance frequencies for seventeen tetrachloro(carboxylato)antimony V compounds, RCO2SbCl4, are reported. The results confirm the difference in the effects of the substituent on the equatorial chlorine atoms and the axial chlorine atoms of the SbCl4 group, previously remarked in Parts I and II of this series, and this effect has been put on a more quantitative basis by correlating the observed frequencies with the pK’s of the corresponding acids.The compounds with R = isopropyl and R = cyclopropyl both show a phase change in the region of 140 K which may correspond to reorientation of the substituent about the R - CO2 axis.

Homoleptic Bismuth and Antimony Complexes of the Tripodal [Te(NtBu)3]2-Anion

1999 ◽  
Vol 38 (7) ◽  
pp. 1380-1381 ◽  
Author(s):  
Tristram Chivers ◽  
Masood Parvez ◽  
Gabriele Schatte ◽  
Glenn P. A. Yap
Keyword(s):  
Antimony Complexes

scholarly journals Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction

2017 ◽  
Vol 129 (31) ◽  
pp. 9239-9243 ◽  
Author(s):  
Jianbing Jiang ◽  
Kelly L. Materna ◽  
Svante Hedström ◽  
Ke R. Yang ◽  
Robert H. Crabtree ◽  
...  
Keyword(s):  
Main Group ◽  
Group Element ◽  
Proton Reduction ◽  
Main Group Element ◽  
Antimony Complexes
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