Growth of Single-Layered Two-Dimensional Mesoporous Polymer/Carbon Films by Self-Assembly of Monomicelles at the Interfaces of Various Substrates

2015 ◽  
Vol 127 (29) ◽  
pp. 8545-8549 ◽  
Author(s):  
Yin Fang ◽  
Yingying Lv ◽  
Jing Tang ◽  
Hao Wu ◽  
Dingsi Jia ◽  
...  
Keyword(s):  
Self Assembly ◽  
Carbon Films ◽  
Two Dimensional ◽  
Mesoporous Polymer

scholarly journals Template-Free Self-Assembly of Two-Dimensional Polymers into Nano/Microstructured Materials

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3310
Author(s):  
Shengda Liu ◽  
Jiayun Xu ◽  
Xiumei Li ◽  
Tengfei Yan ◽  
Shuangjiang Yu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Recent Progress ◽  
Two Dimensional ◽  
Subsequent Removal ◽  
The Past ◽  
2D Polymers ◽  
Template Free ◽  
Self Assembled ◽  
The Relationship ◽  
Polymer Tubes

In the past few decades, enormous efforts have been made to synthesize covalent polymer nano/microstructured materials with specific morphologies, due to the relationship between their structures and functions. Up to now, the formation of most of these structures often requires either templates or preorganization in order to construct a specific structure before, and then the subsequent removal of previous templates to form a desired structure, on account of the lack of “self-error-correcting” properties of reversible interactions in polymers. The above processes are time-consuming and tedious. A template-free, self-assembled strategy as a “bottom-up” route to fabricate well-defined nano/microstructures remains a challenge. Herein, we introduce the recent progress in template-free, self-assembled nano/microstructures formed by covalent two-dimensional (2D) polymers, such as polymer capsules, polymer films, polymer tubes and polymer rings.

General Interfacial Self‐Assembly Engineering for Patterning Two‐Dimensional Polymers with Cylindrical Mesopores on Graphene

2019 ◽  
Vol 58 (30) ◽  
pp. 10173-10178 ◽  
Author(s):  
Hao Tian ◽  
Jieqiong Qin ◽  
Dan Hou ◽  
Qian Li ◽  
Chen Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Two Dimensional

Percolation in two-dimensional nanoparticle films from colloidal self-assembly

2007 ◽  
Vol 204 (6) ◽  
pp. 1856-1862 ◽  
Author(s):  
Ching-Ling Hsu ◽  
Szu-Ming Chu ◽  
Kiwi Wood ◽  
Yi-Rong Yang
Keyword(s):  
Self Assembly ◽  
Two Dimensional ◽  
Nanoparticle Films

Self-assembly of carbon nanotubes into two-dimensional geometries using DNA origami templates

2009 ◽  
Vol 5 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Hareem T. Maune ◽  
Si-ping Han ◽  
Robert D. Barish ◽  
Marc Bockrath ◽  
William A. Goddard III ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Self Assembly ◽  
Dna Origami ◽  
Two Dimensional

Square-grid coordination networks of (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) in its clathrate with two guest molecules of 1,2-dichlorobenzene: supramolecular isomerism of the porphyrin self-assembly

2009 ◽  
Vol 65 (3) ◽  
pp. m139-m142 ◽  
Author(s):  
Rajesh Koner ◽  
Israel Goldberg
Keyword(s):  
Self Assembly ◽  
Metal Ion ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Coordination Networks ◽  
Guest Molecules ◽  
Square Grid ◽  
Supramolecular Isomerism ◽  
Self Assembled ◽  
Solvent Molecules

The title compound, (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) 1,2-dichlorobenzene disolvate, [Zn(C40H24N8)]·2C6H4Cl2, contains a clathrate-type structure. It is composed of two-dimensional square-grid coordination networks of the self-assembled porphyrin moiety, which are stacked one on top of the other in a parallel manner. The interporphyrin cavities of the overlapping networks combine into channel voids accommodated by the dichlorobenzene solvent. Molecules of the porphyrin complex are located on crystallographic inversion centres. The observed two-dimensional assembly mode of the porphyrin units represents a supramolecular isomer of the unique three-dimensional coordination frameworks of the same porphyrin building block observed earlier. The significance of this study lies in the discovery of an additional supramolecular isomer of the rarely observed structures of metalloporphyrins self-assembled directly into extended coordination polymers without the use of external ligand or metal ion auxiliaries.

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