Fluxionally Chiral DMAP Catalysts: Kinetic Resolution of Axially Chiral Biaryl Compounds

2014 ◽  
Vol 126 (44) ◽  
pp. 12012-12015 ◽  
Author(s):  
Gaoyuan Ma ◽  
Jun Deng ◽  
Mukund P. Sibi
Keyword(s):  
Kinetic Resolution ◽  
Axially Chiral ◽  
Biaryl Compounds

ChemInform Abstract: Synthesis of Axially Chiral Biaryl Compounds by Asymmetric Catalytic Reactions with Transition Metals

ChemInform ◽  
2016 ◽  
Vol 47 (18) ◽  
Author(s):  
Pauline Loxq ◽  
Eric Manoury ◽  
Rinaldo Poli ◽  
Eric Deydier ◽  
Agnes Labande
Keyword(s):  
Transition Metals ◽  
Catalytic Reactions ◽  
Asymmetric Catalytic ◽  
Axially Chiral ◽  
Biaryl Compounds

Atroposelective Transfer Hydrogenation of Biaryl Aminals via Dynamic Kinetic Resolution. Synthesis of Axially Chiral Diamines

ACS Catalysis ◽  
2021 ◽  
pp. 4117-4124
Author(s):  
José A. Carmona ◽  
Carlos Rodríguez-Franco ◽  
Joaquín López-Serrano ◽  
Abel Ros ◽  
Javier Iglesias-Sigüenza ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
Axially Chiral ◽  
Chiral Diamines

Organocatalytic Asymmetric Methodologies towards the Synthesis of Atropisomeric N-Heterocycles

Synthesis ◽  
2020 ◽  
Vol 52 (17) ◽  
pp. 2450-2468
Author(s):  
Vasco Corti ◽  
Giulio Bertuzzi
Keyword(s):  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Chirality Transfer ◽  
Axial Chirality ◽  
Axially Chiral ◽  
Molecular Architectures

A perspective on the literature dealing with the organocatalytic asymmetric preparation of axially chiral N-heterocycles is provided. A particular focus is devoted to rationalize the synthetic strategies employed in each case. Moreover, specific classes of organocatalysts are shown to stand out as privileged motives for the stereoselective preparation of such synthetically challenging molecular architectures. Finally, an overview of the main trends in the field is given.1 Introduction2 Five-Membered Rings2.1 Arylation2.2 Dynamic Kinetic Resolution2.3 Ring Construction2.4 Central-to-Axial Chirality Conversion and Chirality Transfer2.5 Desymmetrization3 Six-Membered Rings3.1 Desymmetrization3.2 (Dynamic) Kinetic Resolution3.3 Ring Construction3.4 Central-to-Axial Chirality Conversion4 Conclusion

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