Nanoparticle Growth in Supported Nickel Catalysts during Methanation Reaction-Larger is Better

2014 ◽  
Vol 126 (36) ◽  
pp. 9647-9651 ◽  
Author(s):  
Peter Munnik ◽  
Marjolein E. Z. Velthoen ◽  
Petra E. de Jongh ◽  
Krijn P. de Jong ◽  
Cedric J. Gommes
2014 ◽  
Vol 53 (36) ◽  
pp. 9493-9497 ◽  
Author(s):  
Peter Munnik ◽  
Marjolein E. Z. Velthoen ◽  
Petra E. de Jongh ◽  
Krijn P. de Jong ◽  
Cedric J. Gommes

2021 ◽  
pp. 150421
Author(s):  
Wojciech Gac ◽  
Witold Zawadzki ◽  
Grzegorz Słowik ◽  
Marcin Kuśmierz ◽  
Stanislaw Dzwigaj

Catalysts ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 13
Author(s):  
Wojciech Gac ◽  
Witold Zawadzki ◽  
Magdalena Greluk ◽  
Grzegorz Słowik ◽  
Marek Rotko ◽  
...  

The influence of Ce and W promoters on the performance of alumina-supported nickel catalysts in the CO2 methanation reaction was investigated. The catalysts were obtained by the co-impregnation method. Nitrogen low-temperature adsorption, temperature-programmed reduction, hydrogen desorption, transmission electron microscopy, X-ray diffraction, and photoelectron spectroscopy studies were used for catalyst characterization. An introduction of Ce and W promoters (1–5 wt %) led to the decrease in mean Ni crystallite size. Gradual increase in the active surface area was observed only for Ce-promoted catalysts. The increase in CO2 conversion in methanation reaction at low-reaction temperatures carried out over Ce-promoted catalysts was attributed to the increase in the active surface area and changes in the redox properties. The introduction of small amounts of tungsten led to an increase in the activity of catalysts, although a decrease in the active surface area was observed. Quasi in situ XPS studies revealed changes in the oxidation state of tungsten under CO2 methanation reaction conditions, indicating the participation of redox promoter changes in the course of surface reactions, leading to an improvement in the activity of the catalyst.


2013 ◽  
Vol 33 (7) ◽  
pp. 1176-1182
Author(s):  
Xinxing WANG ◽  
Xueguang WANG ◽  
Xingfu SHANG ◽  
Wangxin NIE ◽  
Xiujing ZOU ◽  
...  

2021 ◽  
Vol 23 (3) ◽  
pp. 1353-1360
Author(s):  
Xiaodong Liu ◽  
Xiaohao Liu ◽  
Ning Li ◽  
Peiyong Ma ◽  
Ying Zhang

A series of Ni/ZrPx catalysts with precisely regulated acid and hydrogenation sites were prepared to study the structure–activity relationship for sorbitol production directly from microcrystalline cellulose and raw biomass.


2021 ◽  
Vol 35 (4) ◽  
pp. 3307-3314
Author(s):  
Yahong Han ◽  
Jinxian Zhao ◽  
Yanhong Quan ◽  
Shunan Yin ◽  
Shiping Wu ◽  
...  

1989 ◽  
Vol 18 (5) ◽  
pp. 777-780 ◽  
Author(s):  
Yoshio Uemichi ◽  
Takeshi Sakai ◽  
Takaji Kanazuka

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