Electrogenerated Chemiluminescence of Donor-Acceptor Molecules with Thermally Activated Delayed Fluorescence

2014 ◽  
Vol 126 (27) ◽  
pp. 7113-7116 ◽  
Author(s):  
Ryoichi Ishimatsu ◽  
Shigeyuki Matsunami ◽  
Takashi Kasahara ◽  
Jun Mizuno ◽  
Tomohiko Edura ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Electrogenerated Chemiluminescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Acceptor Molecules

Electrogenerated Chemiluminescence of Donor-Acceptor Molecules with Thermally Activated Delayed Fluorescence

2014 ◽  
Vol 53 (27) ◽  
pp. 6993-6996 ◽  
Author(s):  
Ryoichi Ishimatsu ◽  
Shigeyuki Matsunami ◽  
Takashi Kasahara ◽  
Jun Mizuno ◽  
Tomohiko Edura ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Electrogenerated Chemiluminescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Acceptor Molecules

scholarly journals Fast Delayed Emission in New Pyridazine-Based Compounds

2021 ◽  
Vol 8 ◽  
Author(s):  
Simonas Krotkus ◽  
Tomas Matulaitis ◽  
Stefan Diesing ◽  
Graeme Copley ◽  
Emily Archer ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Intersystem Crossing ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Emission Lifetime ◽  
Donor Acceptor ◽  
Acceptor Moiety ◽  
Triplet Harvesting ◽  
Acceptor Molecules

Three novel donor-acceptor molecules comprising the underexplored pyridazine (Pydz) acceptor moiety have been synthesized and their structural, electrochemical and photophysical properties thoroughly characterized. Combining Pydz with two phenoxazine donor units linked via a phenyl bridge in a meta configuration (dPXZMePydz) leads to high reverse intersystem crossing rate kRISC = 3.9 · 106 s−1 and fast thermally activated delayed fluorescence (TADF) with <500 ns delayed emission lifetime. Efficient triplet harvesting via the TADF mechanism is demonstrated in OLEDs using dPXZMePydz as the emitter but does not occur for compounds bearing weaker donor units.

scholarly journals Novel phenoxazine-benzonitrile and phenothiazine-benzonitrile donor-acceptor molecules with thermally activated delayed fluorescence (TADF)

2020 ◽  
Vol 175 ◽  
pp. 108114 ◽  
Author(s):  
Faiza Baraket ◽  
Bruno Pedras ◽  
Érica Torres ◽  
Maria João Brites ◽  
Mohamed Dammak ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Acceptor Molecules

Novel thermally activated delayed fluorescence materials by high-throughput virtual screening: going beyond donor–acceptor design

2021 ◽  
Vol 9 (9) ◽  
pp. 3324-3333 ◽  
Author(s):  
Ke Zhao ◽  
Ömer H. Omar ◽  
Tahereh Nematiaram ◽  
Daniele Padula ◽  
Alessandro Troisi
Keyword(s):  
Virtual Screening ◽  
Quantum Chemistry ◽  
High Throughput ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quantum Chemistry Calculations ◽  
Donor Acceptor ◽  
Molecular Semiconductors ◽  
High Throughput Virtual Screening

125 potential TADF candidates are identified through quantum chemistry calculations of 700 molecules derived from a database of 40 000 molecular semiconductors. Most of them are new and some do not belong to the class of donor–acceptor molecules.

scholarly journals Regioisomeric Effect on the Excited-State Fate Leading to Room-Temperature Phosphorescence or Thermally Activated Delayed Fluorescence in a Dibenzophenazine-Cored Donor–Acceptor–Donor System

2021 ◽  
Author(s):  
Takumi Hosono ◽  
Nicolas Oliveira Decarli ◽  
Paola Zimmermann Crocomo ◽  
Tsuyoshi Goya ◽  
Leonardo Evaristo de Sousa ◽  
...  
Keyword(s):  
Excited State ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Quantum Yields ◽  
Room Temperature Phosphorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Emission Behavior

Exploring design principle for switching thermally activated dealyed fluorescecne (TADF) and room temperature phosphorescence (RTP) is a fundamentally imporant research in developing triplet-mediated photofunctional organic materials. Herein systematic studies on the regioisomeric and substituents effects in a twisted donor–acceptor–donor (D–A–D) scaffold (A = dibenzo[a,j]phenazine; D = dihydrophenazasiline) on the fate of the excited state have been performed. The study revealed that the regiosiomerism clearly affects the emission behavior of the D–A–D compounds. Distinct difference in TADF, dual TADF & RTP, and dual RTP were observed, depending on the host used. Furthermore, OLED organic light-emitting diodes (OLEDs) fabricated with the developed emitters achieved high external quantum yields for RTP-based OLEDS up to 7.4%.

scholarly journals Synthesis and optoelectronic properties of benzoquinone-based donor–acceptor compounds

2019 ◽  
Vol 15 ◽  
pp. 2914-2921
Author(s):  
Daniel R Sutherland ◽  
Nidhi Sharma ◽  
Georgina M Rosair ◽  
Ifor D W Samuel ◽  
Ai-Lan Lee ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Delayed Fluorescence ◽  
Optoelectronic Properties ◽  
Donor Group ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Palladium Catalyzed ◽  
Donor Acceptor

Herein, we report a mild and efficient palladium-catalyzed C–H functionalization method to synthesize a series of benzoquinone (BQ)-based charge-transfer (CT) derivatives in good yields. The optoelectronic properties of these compounds were explored both theoretically and experimentally and correlations to their structures were identified as a function of the nature and position of the donor group (meta and para) attached to the benzoquinone acceptor. Compound 3, where benzoquinone is para-conjugated to the diphenylamine donor group, exhibited thermally activated delayed fluorescence (TADF) with a biexponential lifetime characterized by a prompt ns component and a delayed component of 353 μs.

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