Polymeric Schiff Bases as Low-Voltage Redox Centers for Sodium-Ion Batteries

2014 ◽  
Vol 126 (21) ◽  
pp. 5445-5449 ◽  
Author(s):  
Elizabeth Castillo-Martínez ◽  
Javier Carretero-González ◽  
Michel Armand
Keyword(s):  
Schiff Bases ◽  
Low Voltage ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Redox Centers

Polymeric Schiff Bases as Low-Voltage Redox Centers for Sodium-Ion Batteries

2014 ◽  
Vol 53 (21) ◽  
pp. 5341-5345 ◽  
Author(s):  
Elizabeth Castillo-Martínez ◽  
Javier Carretero-González ◽  
Michel Armand
Keyword(s):  
Schiff Bases ◽  
Low Voltage ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Redox Centers

Oligomeric-Schiff bases as negative electrodes for sodium ion batteries: unveiling the nature of their active redox centers

2015 ◽  
Vol 8 (11) ◽  
pp. 3233-3241 ◽  
Author(s):  
María López-Herraiz ◽  
Elizabeth Castillo-Martínez ◽  
Javier Carretero-González ◽  
Javier Carrasco ◽  
Teófilo Rojo ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Anode Materials ◽  
Low Cost ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Redox Active ◽  
Negative Electrodes ◽  
Redox Centers

Novel hybrids between carboxylate and aromatic Schiff base show reversible sodium insertion below 1.2 V vs. Na+. Identifying the redox active units leads to sustainable and low cost anode materials beyond 250 mA h g−1.

A P2/P3 composite-layered cathode material with low-voltage decay for sodium-ion batteries

2021 ◽  
Author(s):  
Xiaoli Chen ◽  
Jiangping Song ◽  
Junsheng Li ◽  
Haining Zhang ◽  
Haolin Tang
Keyword(s):  
Cathode Material ◽  
Low Voltage ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Voltage Decay

Extended low-voltage plateau capacity of hard carbon spheres anode for sodium ion batteries

2020 ◽  
Vol 476 ◽  
pp. 228550
Author(s):  
Xiang Zhang ◽  
Xiaoli Dong ◽  
Xuan Qiu ◽  
Yongjie Cao ◽  
Congxiao Wang ◽  
...  
Keyword(s):  
Low Voltage ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Carbon Spheres ◽  
Hard Carbon ◽  
Voltage Plateau

scholarly journals Self-supported binder-free hard carbon electrodes for sodium-ion batteries: insights into their sodium storage mechanisms

2020 ◽  
Vol 8 (11) ◽  
pp. 5558-5571 ◽  
Author(s):  
Adrian Beda ◽  
Claire Villevieille ◽  
Pierre-Louis Taberna ◽  
Patrice Simon ◽  
Camélia Matei Ghimbeu
Keyword(s):  
Phenolic Resin ◽  
Low Voltage ◽  
Sodium Ion ◽  
Carbon Electrodes ◽  
Sodium Ion Batteries ◽  
Hard Carbon ◽  
Binder Free ◽  
Voltage Plateau ◽  
Filter Papers ◽  
Sodium Storage

Binder-free self-supported hard carbon electrodes derived from biopolymer filter papers impregnated with phenolic resin were designed to study Na storage mechanisms. Experimental evidence of Na intercalation in the low voltage plateau was found.

scholarly journals Advanced anode materials for sodium ion batteries: carbodiimides

MRS Advances ◽  
2017 ◽  
Vol 2 (21-22) ◽  
pp. 1165-1176 ◽  
Author(s):  
Aitor Eguia-Barrio ◽  
Elizabeth Castillo-Martinez ◽  
Xiaohui Liu ◽  
Richard Dronskowski ◽  
Luis Lezama ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Low Voltage ◽  
Reversible Capacity ◽  
Sodium Ion ◽  
Enthalpies Of Formation ◽  
Sodium Ion Batteries ◽  
Sem Images ◽  
Conversion Reaction ◽  
Micrometer Particle ◽  
Voltage Plateau

ABSTRACTTMNCN (where TM = Mn2+, Fe2+, Co2+ or Ni2+) have been recently proposed as electrochemically active materials for Na-ion insertion that operate via conversion reaction. Their electrochemical performance for Na-ion batteries is presented here with an emphasis on long-term cycling. With a very low voltage for Na insertion of ∼0.1V vs Na+/Na for MnNCN, the overpotential observed in batteries of MnNCN plays a very important role in their performance, evidencing big differences in the electrochemical performance between materials produced with different nano- and micrometer particle sizes evidenced by SEM images. A more suitable voltage for the conversion reaction accompanied by less overpotential is shown by FeNCN, CoNCN and NiNCN. Despite the lower reversible capacity achieved by FeNCN (450 mAh/g) in comparison with CoNCN and NiNCN in the first cycle; the smallest first-cycle irreversible capacity (220 mAh/g) and the lower voltage plateau (0.3 V vs Na+/Na) make FeNCN a good candidate as an anode material for sodium ion batteries. The voltages of conversion reaction are correlated with the calculated enthalpies of formation suggesting that thermodynamics dominates the observed electrochemical conversion reaction.

CuS2 sheets: a hidden anode material with a high capacity for sodium-ion batteries

2021 ◽  
Author(s):  
Shaohua Lu ◽  
Weidong Hu ◽  
Xiaojun Hu
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Low Cost ◽  
High Capacity ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Due to their low cost and improved safety compared to lithium-ion batteries, sodium-ion batteries have attracted worldwide attention in recent decades.

Synthesis of N-doped straw sheaf–like porous MnO@C composite as anode of advanced lithium-/sodium-ion batteries

Ionics ◽  
2020 ◽  
Author(s):  
Rundie Liu ◽  
Zhenguo Wu ◽  
Qin Hu ◽  
Gongke Wang ◽  
Yuxia Liu ◽  
...  
Keyword(s):  
Sodium Ion ◽  
Sodium Ion Batteries

A novel design strategy of a practical carbon anode material from a single lignin-based surfactant source for sodium-ion batteries

2020 ◽  
Vol 56 (45) ◽  
pp. 6078-6081 ◽  
Author(s):  
Changhao Li ◽  
Yi Sun ◽  
Qiujie Wu ◽  
Xin Liang ◽  
Chunhua Chen ◽  
...  
Keyword(s):  
Anode Material ◽  
Design Strategy ◽  
Sodium Ion ◽  
Carbon Anode ◽  
Sodium Ion Batteries ◽  
Lignin Sulfonate ◽  
Novel Design

A schematic illustration showing the preparation of HCM from a single sodium lignin sulfonate source and the process of Na storage.

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