Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2under Ambient Conditions

2014 ◽  
Vol 126 (10) ◽  
pp. 2653-2657 ◽  
Author(s):  
Wen-Yang Gao ◽  
Yao Chen ◽  
Youhong Niu ◽  
Kia Williams ◽  
Lindsay Cash ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Ambient Conditions ◽  
Metal Organic ◽  
Organic Framework

Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2under Ambient Conditions

2014 ◽  
Vol 53 (10) ◽  
pp. 2615-2619 ◽  
Author(s):  
Wen-Yang Gao ◽  
Yao Chen ◽  
Youhong Niu ◽  
Kia Williams ◽  
Lindsay Cash ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Ambient Conditions ◽  
Metal Organic ◽  
Organic Framework

Design and synthesis of a new magnetic metal organic framework as a versatile platform for immobilization of acidic catalysts and CO2 fixation reaction

2021 ◽  
Author(s):  
Faezeh Taghavi ◽  
Amir Khojastehnezhad ◽  
Reza Khalifeh ◽  
Maryam Rajabzadeh ◽  
Fahimeh Rezaei ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
Chemical Fixation ◽  
Design And Synthesis ◽  
Acidic Catalysts ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Fixation Reaction ◽  
Organic Framework

The first report of the use of an acidic magnetic metal organic framework for the chemical fixation of CO2 as an environmentally friendly reaction.

A New Multi-Functional Cu(II)-Organic Framework as a Platform for Selective Carbon Dioxide Chemical Fixation and Separation of Organic Dyes

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yang-Tian Yan ◽  
Chen-Yang Wang ◽  
Li-Na Zheng ◽  
Yun-Long Wu ◽  
Jiao Liu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Benzoic Acid ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Acid Ligand ◽  
Metal Organic ◽  
Organic Framework

A new multi-functional metal-organic framework, {[Cu2(HL)(H2O)2]·NMP·2H2O}n (1), was assembled employing a asymmetrical V-shaped rigid multicarboxylic acid ligand H5L (H5L= 2,4-di(2′,5′-dicarboxylphenyl)benzoic acid) with Cu(II) ions. 1 possesses a 3D pore formed...

scholarly journals Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel walls

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160031 ◽  
Author(s):  
Rebecca Smith ◽  
Iñigo J. Vitórica-Yrezábal ◽  
Adrian Hill ◽  
Lee Brammer
Keyword(s):  
Nmr Spectroscopy ◽  
Metal Organic Framework ◽  
Magic Angle Spinning ◽  
Nitrogen Atmosphere ◽  
Magic Angle ◽  
Ambient Conditions ◽  
Solid State Transformation ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework (MOF) with one-dimensional channels of approximately hexagonal cross-section [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)] 1 (TMP =2,3,5,6-tetramethylpyrazine) has been synthesized with MeOH filling the channels in its as-synthesized form as [Ag 2 (O 2 CCF 2 CF 2 CO 2 )(TMP)]· n (MeOH) 1-MeOH ( n  = 1.625 by X-ray crystallography). The two types of ligand connect columns of Ag(I) centres in an alternating manner, both around the channels and along their length, leading to an alternating arrangement of hydrocarbon (C–H) and fluorocarbon (C–F) groups lining the channel walls, with the former groups projecting further into the channel than the latter. MeOH solvent in the channels can be exchanged for a variety of arene guests, ranging from xylenes to tetrafluorobenzene, as confirmed by gas chromatography, 1 H nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis and 13 C cross-polarization magic angle spinning NMR spectroscopy. Alkane and perfluoroalkane guests, however, do not enter the channels. Although exhibiting some stability under a nitrogen atmosphere, sufficient to enable crystal structure determination, the evacuated MOF 1 is unstable for periods of more than minutes under ambient conditions or upon heating, whereupon it undergoes an irreversible solid-state transformation to a non-porous polymorph 2 , which comprises Ag 2 (O 2 CCF 2 CF 2 CO 2 ) coordination layers that are pillared by TMP ligands. This transformation has been followed in situ by powder X-ray diffraction and shown to proceed via a crystalline intermediate. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

scholarly journals Direct evidence for 2-fold to 3-fold change of interpenetration in a MOF

2014 ◽  
Vol 70 (a1) ◽  
pp. C636-C636
Author(s):  
Himanshu Aggarwal ◽  
Prashant Bhatt ◽  
Charl Benzuidenhout ◽  
Leonard Barbour
Keyword(s):  
Single Crystal ◽  
Crystal Engineering ◽  
Molecular Level ◽  
Metal Organic Framework ◽  
Structural Rearrangement ◽  
Structure Property ◽  
Ambient Conditions ◽  
Physical Conditions ◽  
Structure Property Relationships ◽  
Metal Organic

Single-crystal to single-crystal transformations has recently received much attention in the field of crystal engineering. Such transformations not only provide insight into the changes taking place within the crystal at the molecular level, but they also aid our understanding of the structure-property relationships. Discrete crystals have been shown to tolerate considerable dynamic behavior at the molecular level while maintaining their single-crystal character. Examples that are common in the literature include bond formation/cleavage,[1] guest uptake,[2] release or exchange as well as polymorphic phase transformations. However, there are rare examples of the structural transformations on the host framework initiated by removal of guest or change in physical conditions such as temperature or pressure. We have investigated a known doubly-interpenetrated metal organic framework with the formula [Zn2(ndc)2(bpy)] which possesses minimal porosity when activated. We have shown not only that the material converts to its triply-interpenetrated analogue upon desolvation, but that the transformation occurs in a single-crystal to single-crystal manner under ambient conditions.[3] This contribution probes the limits to which a single-crystal material can undergo structural rearrangement while still maintaining the macroscopic integrity of the crystal as a discrete entity.

Multitask Guanidinium Bromide Functionalized Metal–Organic Framework in Chemical Fixation of CO2 at Low Pressure and Temperature

2019 ◽  
Vol 58 (8) ◽  
pp. 2784-2791 ◽  
Author(s):  
Ahmad Shaabani ◽  
Reza Mohammadian ◽  
Hassan Farhid ◽  
Masoumeh Karimi Alavijeh ◽  
Mostafa M. Amini
Keyword(s):  
Metal Organic Framework ◽  
Low Pressure ◽  
Chemical Fixation ◽  
Metal Organic ◽  
Organic Framework

NO2 Removal under Ambient Conditions by Nanoporous Multivariate Zirconium-Based Metal–Organic Framework

2020 ◽  
Vol 3 (11) ◽  
pp. 11442-11454
Author(s):  
Xinbo Wang ◽  
Zhenzhu Xu ◽  
Li Li ◽  
Yue Zhao ◽  
Ruyue Su ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Ambient Conditions ◽  
Metal Organic ◽  
Organic Framework
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