CO Cross-Coupling of Activated Aryl and Heteroaryl Halides with Aliphatic Alcohols

2012 ◽  
Vol 124 (36) ◽  
pp. 9205-9208 ◽  
Author(s):  
Peter E. Maligres ◽  
Jing Li ◽  
Shane W. Krska ◽  
John D. Schreier ◽  
Izzat T. Raheem
Keyword(s):  
Cross Coupling ◽  
Aliphatic Alcohols

ChemInform Abstract: Novel Route for the Construction of Chroman Ring System Using Cross-Coupling Between Benzylic and Aliphatic Alcohols in the Presence of NaHSO4/SiO2.

ChemInform ◽  
2016 ◽  
Vol 47 (1) ◽  
Author(s):  
Tadashi Aoyama ◽  
Takuya Furukawa ◽  
Mamiko Hayakawa ◽  
Toshio Takido ◽  
Mitsuo Kodomari
Keyword(s):  
Cross Coupling ◽  
Ring System ◽  
Aliphatic Alcohols ◽  
Chroman Ring

CO Cross-Coupling of Activated Aryl and Heteroaryl Halides with Aliphatic Alcohols

2012 ◽  
Vol 51 (36) ◽  
pp. 9071-9074 ◽  
Author(s):  
Peter E. Maligres ◽  
Jing Li ◽  
Shane W. Krska ◽  
John D. Schreier ◽  
Izzat T. Raheem
Keyword(s):  
Cross Coupling ◽  
Aliphatic Alcohols

Palladium-Catalyzed Csp3–H Bond mono-Aroyloxylation of O-Alkyl Substituted 2,4,6-Trimethoxybenzaldoxime Ethers

Synlett ◽  
2018 ◽  
Vol 29 (09) ◽  
pp. 1249-1255
Author(s):  
Wen-Li Qiao ◽  
Ling-Yan Shao ◽  
Ya-Hua Hu ◽  
Li-Hao Xing ◽  
Ke-Zuan Deng ◽  
...  
Keyword(s):  
Aromatic Ring ◽  
Aliphatic Alcohol ◽  
Cross Coupling ◽  
Aliphatic Alcohols ◽  
Aromatic Acid ◽  
Rapid Access ◽  
Site Selectivity ◽  
Wide Range ◽  
Palladium Catalyzed ◽  
Directing Group

A palladium-catalyzed Csp3–H bond mono-aroyloxylation of O-alkyl substituted oxime ethers has been developed by using 2,4,6-trimethoxybenzaldoxime as an exo-type directing group with exclusive site-selectivity. With the wide range of masked aliphatic alcohol substrates and aromatic acid coupling partners, the protocol allows rapid access to various 2-alkyl substituted glycol derivatives in synthetically useful to good yields. The employed directing group is readily removed, accordingly affording valuable functionalized aliphatic alcohols. When the solvent from hybrid DCE/HFIP to CH3CN, non-directed oxidative cross-coupling is observed between the electron-rich aromatic ring of substrates and aromatic acid partners.

scholarly journals Au(iii)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis

2017 ◽  
Vol 8 (2) ◽  
pp. 946-952 ◽  
Author(s):  
Jordi Serra ◽  
Teodor Parella ◽  
Xavi Ribas
Keyword(s):  
Cross Coupling ◽  
Reactive Intermediates ◽  
Aliphatic Alcohols ◽  
Coupling Processes

Au(iii)-aryl species have been crystallographically isolated as reactive intermediates in oxidant-free C–O and C–N cross coupling processes, using aromatic and aliphatic alcohols and amines, as well as water and amides, as nucleophiles.

Novel Route for the Construction of Chroman Ring System Using Cross-Coupling between Benzylic and Aliphatic Alcohols in the Presence of NaHSO4/SiO2

Synlett ◽  
2015 ◽  
Vol 26 (13) ◽  
pp. 1875-1879 ◽  
Author(s):  
Tadashi Aoyama ◽  
Takuya Furukawa ◽  
Mamiko Hayakawa ◽  
Toshio Takido ◽  
Mitsuo Kodomari
Keyword(s):  
Cross Coupling ◽  
Ring System ◽  
Aliphatic Alcohols ◽  
Chroman Ring

ChemInform Abstract: C-O Cross-Coupling of Activated Aryl and Heteroaryl Halides with Aliphatic Alcohols.

ChemInform ◽  
2013 ◽  
Vol 44 (6) ◽  
pp. no-no
Author(s):  
Peter E. Maligres ◽  
Jing Li ◽  
Shane W. Krska ◽  
John D. Schreier ◽  
Izzat T. Raheem
Keyword(s):  
Cross Coupling ◽  
Aliphatic Alcohols
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