Asymmetric Autocatalysis: Triggered by Chiral Isotopomer Arising from Oxygen Isotope Substitution

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...  

Effect of the partial oxygen isotope substitution on (Pr1-yEuy)0.7Ca0.3CoO3 cobaltites was studied in detail for the crossover region (0.12<у<0.26) of the phase diagram. We prepared a series of the cobaltite samples with the different degrees of enrichment by the heavy oxygen isotope 18O, namely, containing 90%, 67%, 43%, 17%, and 0% of 18O. The Eu doping of the samples was chosen to be near and on the both sides of the crossover doping level ycr. Based on measurements of the ac magnetic susceptibility χ(Т) and electrical resistivity ρ(Т), we were able to analyze the evolution the sample properties with the change Eu and 18O content.


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