Selective Deoxygenation of Epoxides to Alkenes with Molecular Hydrogen Using a Hydrotalcite-Supported Gold Catalyst: A Concerted Effect between Gold Nanoparticles and Basic Sites on a Support

2011 ◽  
Vol 123 (13) ◽  
pp. 3042-3045 ◽  
Author(s):  
Akifumi Noujima ◽  
Takato Mitsudome ◽  
Tomoo Mizugaki ◽  
Koichiro Jitsukawa ◽  
Kiyotomi Kaneda
Keyword(s):  
Gold Nanoparticles ◽  
Molecular Hydrogen ◽  
Gold Catalyst ◽  
Basic Sites ◽  
Supported Gold ◽  
Selective Deoxygenation

scholarly journals Catalytic Activity of Beta-Cyclodextrin-Gold Nanoparticles Network in Hydrogen Evolution Reaction

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 118
Author(s):  
Qui Quach ◽  
Erik Biehler ◽  
Ahmed Elzamzami ◽  
Clay Huff ◽  
Julia M. Long ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Gold Catalyst ◽  
Hydrogen Gas ◽  
Hydrolysis Reaction ◽  
X Ray Diffraction ◽  
Beta Cyclodextrin ◽  
Transmission Electron ◽  
Production Of Hydrogen ◽  
Climate Crisis

The current climate crisis warrants investigation into alternative fuel sources. The hydrolysis reaction of an aqueous hydride precursor, and the subsequent production of hydrogen gas, prove to be a viable option. A network of beta-cyclodextrin capped gold nanoparticles (BCD-AuNP) was synthesized and subsequently characterized by Powder X-Ray Diffraction (P-XRD), Fourier Transform Infrared (FTIR), Transmission Electron Microscopy (TEM), and Ultraviolet-Visible Spectroscopy (UV-VIS) to confirm the presence of gold nanoparticles as well as their size of approximately 8 nm. The catalytic activity of the nanoparticles was tested in the hydrolysis reaction of sodium borohydride. The gold catalyst performed best at 303 K producing 1.377 mL min−1 mLcat−1 of hydrogen. The activation energy of the catalyst was calculated to be 54.7 kJ/mol. The catalyst resisted degradation in reusability trials, continuing to produce hydrogen gas in up to five trials.

Role of Hydroxyl Groups in Low-Temperature CO Catalytic Oxidation over Zn4Si2O7(OH)2 Nanowire-Supported Gold Nanoparticles

2018 ◽  
Vol 122 (44) ◽  
pp. 25456-25466 ◽  
Author(s):  
Jing-Jing Li ◽  
Bao-Lin Zhu ◽  
Gui-Chang Wang ◽  
Zun-Feng Liu ◽  
Wei-Ping Huang ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Low Temperature ◽  
Catalytic Oxidation ◽  
Hydroxyl Groups ◽  
Co Catalytic Oxidation ◽  
Supported Gold Nanoparticles ◽  
Supported Gold

Inside Back Cover: Supported Gold Nanoparticles as Reusable Catalysts for Oxidation Reactions of Industrial Significance (ChemCatChem 7/2017)

ChemCatChem ◽  
2017 ◽  
Vol 9 (7) ◽  
pp. 1354-1354
Author(s):  
Luísa Margarida Dias Ribeiro de Sousa Martins ◽  
Sónia Alexandra Correia Carabineiro ◽  
Jiawei Wang ◽  
Bruno Gonçalo Martins Rocha ◽  
Francisco José Maldonado-Hódar ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Oxidation Reactions ◽  
Back Cover ◽  
Supported Gold Nanoparticles ◽  
Supported Gold
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