Dynamic and Programmable DNA-Templated Boronic Ester Formation

2011 ◽  
Vol 123 (18) ◽  
pp. 4279-4282 ◽  
Author(s):  
Anthony R. Martin ◽  
Ivan Barvik ◽  
Delphine Luvino ◽  
Michael Smietana ◽  
Jean-Jacques Vasseur
Keyword(s):  
Boronic Ester ◽  
Ester Formation

RNA-directed off/on switch of RNase H activity using boronic ester formation

2017 ◽  
Vol 15 (38) ◽  
pp. 8204-8210 ◽  
Author(s):  
Maëva Reverte ◽  
Ivan Barvik ◽  
Jean-Jacques Vasseur ◽  
Michael Smietana
Keyword(s):  
Boronic Acid ◽  
Rnase H ◽  
Boronic Ester ◽  
Ester Formation

A new concept to modulate RNase H activity is presented based on the boronic acid/boronate switch.

Dynamic and Programmable DNA-Templated Boronic Ester Formation

2011 ◽  
Vol 50 (18) ◽  
pp. 4193-4196 ◽  
Author(s):  
Anthony R. Martin ◽  
Ivan Barvik ◽  
Delphine Luvino ◽  
Michael Smietana ◽  
Jean-Jacques Vasseur
Keyword(s):  
Boronic Ester ◽  
Ester Formation

scholarly journals Interdependent Dynamic Nitroaldol and Boronic Ester Reactions for Complex Dynamers of Different Topologies

2021 ◽  
Author(s):  
Antanas Karalius ◽  
Yunchuan Qi ◽  
Mubarak Ayinla ◽  
Zoltan Szabo ◽  
Olof Ramstrom
Keyword(s):  
Dynamic Systems ◽  
Main Chain ◽  
Building Blocks ◽  
Boronic Acids ◽  
Complex Dynamic ◽  
Complex Dynamic Systems ◽  
Boronic Ester ◽  
Ester Formation ◽  
Nitroaldol Reaction ◽  
Hydrolysis Of

Complex dynamic systems displaying interdependency between nitroaldol and boronic ester reactions have been demonstrated. Nitroalkane-1,3-diols, generated by the nitroaldol reaction, were susceptible to ester formation with different boronic acids in aprotic solvents, whereas hydrolysis of the esters occurred in the presence of water. The boronic ester formation led to significant stabilization of the nitroaldol adducts under basic conditions. The use of bifunctional building blocks was furthermore established, allowing for main chain nitroaldol-boronate dynamers as well as complex network dynamers with distinct topologies. The shape and rigidity of the resulting dynamers showed an apparent dependency on the configuration of the boronic acids.

Improved δ-valerolactam templates for the assembly of Aβ-miniamyloids by boronic ester formation

2016 ◽  
Vol 14 (22) ◽  
pp. 5032-5048 ◽  
Author(s):  
André Wuttke ◽  
Sebastian Nils Fischer ◽  
Annika Nebel ◽  
Michael Marsch ◽  
Armin Geyer
Keyword(s):  
Boronic Ester ◽  
Ester Formation ◽  
Amyloidogenic Peptides

Numerically defined oligomers of amyloidogenic peptides were obtained by boronic ester formation with synthetic polyol templates.

Self-Assembly of a Cavitand-Based Capsule by Dynamic Boronic Ester Formation

2008 ◽  
Vol 120 (33) ◽  
pp. 6351-6354 ◽  
Author(s):  
Naoki Nishimura ◽  
Kenji Kobayashi
Keyword(s):  
Self Assembly ◽  
Boronic Ester ◽  
Ester Formation

Control of the reversibility during boronic ester formation: application to the construction of ferrocene dimers and trimers

2017 ◽  
Vol 46 (7) ◽  
pp. 2370-2376 ◽  
Author(s):  
Kosuke Ono ◽  
Yohei Tohyama ◽  
Tatsuhiro Uchikura ◽  
Yuji Kikuchi ◽  
Kotaro Fujii ◽  
...  
Keyword(s):  
Aprotic Solvents ◽  
Boronic Ester ◽  
Ester Formation ◽  
Boronic Esters ◽  
Neutral Conditions

Equilibration of boronic esters during boronic ester formation was controlled using protic or aprotic solvents under neutral conditions.

Reversible Boronic Ester Formation of Ribopyranosylated Glycopeptides

2016 ◽  
Vol 1 (15) ◽  
pp. 4570-4576 ◽  
Author(s):  
Romina A. Kirschner ◽  
Armin Geyer
Keyword(s):  
Boronic Ester ◽  
Ester Formation

Ester formation fromn-alkanes by fungi isolated from aircraft fuel

1970 ◽  
Vol 10 (3) ◽  
pp. 189-196 ◽  
Author(s):  
H. Iizuka ◽  
H. T. Lin ◽  
M. Iida
Keyword(s):  
Aircraft Fuel ◽  
Ester Formation
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