Acid-Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution

2010 ◽  
Vol 123 (6) ◽  
pp. 1403-1406 ◽  
Author(s):  
Vladislava A. Levina ◽  
Andrea Rossin ◽  
Natalia V. Belkova ◽  
Michele R. Chierotti ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Acid Base ◽  
Base Interaction ◽  
Transition Metal Hydrides ◽  
Dihydrogen Bonding ◽  
Acid Base Interaction

Acid-Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution

2010 ◽  
Vol 50 (6) ◽  
pp. 1367-1370 ◽  
Author(s):  
Vladislava A. Levina ◽  
Andrea Rossin ◽  
Natalia V. Belkova ◽  
Michele R. Chierotti ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Acid Base ◽  
Base Interaction ◽  
Transition Metal Hydrides ◽  
Dihydrogen Bonding ◽  
Acid Base Interaction

Bis(cyclopentadienyl)dihydrido Mo and W complexes as Lewis bases — A computational study about their adducts with BX3 (X = F, Cl) and Al(CH3)3

2009 ◽  
Vol 87 (10) ◽  
pp. 1406-1414 ◽  
Author(s):  
Mario Amati ◽  
Francesco Lelj
Keyword(s):  
Transition Metal ◽  
Density Functional ◽  
Computational Study ◽  
Computational Investigation ◽  
Acid Base ◽  
Base Interaction ◽  
Lewis Bases ◽  
Functional Methods ◽  
Acid Base Interaction

A computational investigation about the Lewis acid–base adducts between bases Cp2MH2 (M = Mo, W) and acids BX3 (X = F, Cl) and Al(CH3)3 is presented. Density functional methods based on pure and hybrid correlation-exchange functionals and relativistic corrections based on the zero order relativistic approximation (ZORA) have been applied. A comparison with experimental data has been addressed to give insights about the nature of the acid–base interaction with the aim to evaluate the role of the transition metal in charge donation toward the acid centre. In this respect, the likelihood of proposed criteria for recognizing the presence of transition-metal direct charge donation has been discussed.

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation
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