Single-Site, Single-Component Catalysts for Very High Molecular Weight Polyethylene: A Robust “Ready-To-Go” Vanadium π-Bonded Complex Without a Preformed VC Bond

2007 ◽  
Vol 119 (32) ◽  
pp. 6231-6234 ◽  
Author(s):  
Amir Jabri ◽  
Ilia Korobkov ◽  
Sandro Gambarotta ◽  
Robbert Duchateau
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Single Component ◽  
Single Site ◽  
Very High

scholarly journals The multiple complexes formed by the interaction of platelet factor 4 with heparin

1980 ◽  
Vol 191 (3) ◽  
pp. 769-776 ◽  
Author(s):  
P E Bock ◽  
M Luscombe ◽  
S E Marshall ◽  
D S Pepper ◽  
J J Holbrook
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Chain Length ◽  
Salt Concentration ◽  
Human Platelet ◽  
Platelet Factor 4 ◽  
High Protein ◽  
Platelet Factor ◽  
The Stability ◽  
Very High

The anisotropy of the fluorescence of dansyl (5-dimethylaminonaphthalene-1- sulphonyl) groups covalently attached to human platelet factor 4 was used to detect the macromolecular compounds formed when the factor was mixed with heparin. At low heparin/protein ratios a very-high-molecular-weight compound (1) was formed that dissociated to give a smaller compound (2) when excess heparin was added. 2. A large complex was also detected as a precipitate that formed at high protein concentrations in chloride buffer. It contained 15.7% (w/w) polysaccharide, equivalent to four or five heparin tetrasaccharide units per protein tetramer. In this complex, more than one molecule of protein binds to each heparin molecule of molecular weight greater than about 6 × 10(3).3. The stability of these complexes varied with pH, salt concentration and the chain length of the heparin. The limit complexes found in excess of the larger heparins consisted of only one heparin molecule per protein tetramer, and the failure to observe complexes with four heparin molecules/protein tetramer is discussed.

Mixing of Carbon Black with Rubber. VI. Analysis of NR/SBR Blends

1988 ◽  
Vol 61 (4) ◽  
pp. 609-618 ◽  
Author(s):  
George R. Cotten ◽  
Lawrence J. Murphy
Keyword(s):  
Molecular Weight ◽  
Carbon Black ◽  
High Molecular Weight ◽  
Surface Area ◽  
Bound Rubber ◽  
Very High

Abstract The distribution of carbon black in NR/SBR blends was determined through the analysis of bound rubber. The NR/SBR blends were found to be very different from the previously studied SBR/BR compounds: these differences were assigned to mutual insolubility of the two polymers and a very high molecular weight of NR. In NR/SBR blends, it was found that changes in molecular weight of the polymer has no effect on the carbon black distribution in the blend. While the “activity” of carbon black did not affect the distribution, the loading of the black in NR decreased linearly with increasing surface area of the black. Approximately 35% of normal tread blacks (surface area 80–100 m2/g) was found in the NR phase. However, the bond between NR and carbon black is quite weak, and black continues to migrate into the SBR phase on prolonged mixing or during blending of NR and SBR masterbatches.

Expanding the morphology library of block copolymer self-assemblies with clews of tubules

2017 ◽  
Vol 53 (36) ◽  
pp. 5005-5008 ◽  
Author(s):  
Xiao-Li Sun ◽  
Dong-Ming Liu ◽  
Pan Wang ◽  
Jia-Lin Tan ◽  
Kang-Kang Li ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymer ◽  
High Molecular Weight ◽  
Self Assembly ◽  
High Asymmetry ◽  
Very High

Clews of tubules are reported via block copolymer self-assembly of P4VP-b-PS with both high asymmetry and very high molecular weight.

scholarly journals Drag-Reducing Effect in Solutions of Very High Molecular Weight Polystyrene by the Rolling Ball Method

1988 ◽  
Vol 20 (2) ◽  
pp. 169-173 ◽  
Author(s):  
Kunio Nakamura ◽  
Shinichi Odajima ◽  
Kazuya Kizawa ◽  
Tsurutaro Nakagawa
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Rolling Ball ◽  
Very High
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