Synthesis and Ligand-Exchange Kinetics of the Solvated Trigonal-Prismatic Clusters [W6CCl12L6]2+ (L=dmf, py)

2007 ◽  
Vol 119 (19) ◽  
pp. 3564-3566 ◽  
Author(s):  
Eric J. Welch ◽  
Jeffrey R. Long
Keyword(s):  
Ligand Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of ◽  
Trigonal Prismatic

Probing the ligand exchange kinetics of phenynyl-based ligands on colloidal Au nanoparticles

2021 ◽  
Vol 5 (1) ◽  
pp. 465-471
Author(s):  
Ting Xiang ◽  
Jianpeng Zong ◽  
Wenjia Xu ◽  
Yuhua Feng ◽  
Hongyu Chen
Keyword(s):  
Real Time ◽  
Ligand Exchange ◽  
Au Nanoparticles ◽  
Relative Strength ◽  
Real Time Monitoring ◽  
Exchange Kinetics ◽  
Colloidal Au ◽  
Kinetics Of

We show that phenynyl ligand could readily bind to colloidal Au nanoparticles. By real-time monitoring the SERS during ligand exchange, the relative strength of phenynyls, thiols and PVP ligands, and different phenynyls were successfully ranked.

A NMR Study of the Exchange Kinetics of the Nonamethylimidodiphosphoramide with its Complexes of Diamagnetic Cations

1978 ◽  
Vol 33 (6) ◽  
pp. 684-685 ◽  
Author(s):  
P. R. Rubini ◽  
L. Rodehüser ◽  
J.-J. Delpuech
Keyword(s):  
Nmr Spectroscopy ◽  
Ligand Exchange ◽  
H Nmr ◽  
Nmr Study ◽  
Exchange Kinetics ◽  
Monodentate Ligands ◽  
Kinetics Of

Abstract The ligand exchange on nonamethylimidodiphosphoramide (NIPA) complexes is found to be very slow comparatively to analogous monodentate ligands; the rates determined by 1H or 31P NMR spectroscopy are: k(25°C)=4.3 × 10-2 s-1; 31.6 s-1 • M-1; 3.7 × 104 S-1 • M-1 and 1.35 × 104 s-1 · M-1 for Mg2+, Ca2+, Sr2+ and Li+ cations respectively. For the Al3+, Ga3+, In3+ and Be2+ ions no exchange could be detected by 1H NMR spectroscopy up to 120 °C, indicating rates lower than about 10-3 s-1

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