A Single-Crystal-to-Single-Crystal Transformation Mediated by Argentophilic Forces Converts a Finite Metal Complex into an Infinite Coordination Network

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Irradiation of single crystals of a ladder-like coordination chain with 365 nm UV light induces a regiospecific photochemical [2+2] cycloaddition reaction of each pair of adjacent diolefinic ligands from neighbouring...


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Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
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New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.


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Consiglia Tedesco

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