Visible‐Light‐Mediated Functionalization of Aryl Diazonium Salts

2021 ◽  
Author(s):  
Xin Zhang ◽  
Yaoyao Mei ◽  
Yangyang Li ◽  
Jingang Hu ◽  
Dayun Huang ◽  
...  
Keyword(s):  
Visible Light ◽  
Diazonium Salts

New Avenues in Radical Trifluoromethylselenylation with ­Trifluoromethyl Tolueneselenosulfonate

Synlett ◽  
2018 ◽  
Vol 30 (07) ◽  
pp. 777-782 ◽  
Author(s):  
Clément Ghiazza ◽  
Cyrille Monnereau ◽  
Lhoussain Khrouz ◽  
Maurice Médebielle ◽  
Thierry Billard ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Transition Metal ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Diazonium Salts ◽  
Metal Free ◽  
Luminescence Measurement ◽  
Stable Reagent ◽  
Shelf Stable

We demonstrated that the shelf-stable reagent trifluoromethyl tolueneselenosulfonate can be involved in radical trifluoromethylselenylation. Upon visible-light irradiation, the homolysis of the reagent could take place at room temperature. This finding is explored for unprecedented C(sp2)–SeCF3 and C(sp3)–SeCF3 processes under transition-metal-free conditions. Mechanistic investigations, including cyclic voltammetry, luminescence measurement, and EPR studies, allowed the proposal of plausible mechanisms.1 Introduction.2 Reactivity of Reagent I with Diazonium Salts3 Reactivity of Reagent I with Alkenes and Alkynes4 Conclusion

Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C–H arylation of heteroarenes

2020 ◽  
Vol 56 (44) ◽  
pp. 5901-5904 ◽  
Author(s):  
Erbay Kalay ◽  
Hüseyin Küçükkeçeci ◽  
Haydar Kilic ◽  
Önder Metin
Keyword(s):  
Visible Light ◽  
Black Phosphorus ◽  
Diazonium Salts ◽  
Metal Free ◽  
Visible Light Active ◽  
First Time

We report for the first time the employment of black phosphorus (BP) as a metal free, visible-light-active and reusable heterogeneous photoredox catalyst for the direct C–H arylation of heteroarenes (furan and thiophene) with aryl diazonium salts.

ChemInform Abstract: Synthetic Applications of Aryl Diazonium Salts Enabled by Visible Light Photoredox Catalysis

ChemInform ◽  
2014 ◽  
Vol 45 (44) ◽  
pp. no-no
Author(s):  
Durga Prasad Hari ◽  
Thea Hering ◽  
Burkhard Koenig
Keyword(s):  
Visible Light ◽  
Diazonium Salts ◽  
Photoredox Catalysis

ChemInform Abstract: Synthesis of 3,3-Disubstituted Oxindoles by Visible-Light-Mediated Radical Reactions of Aryl Diazonium Salts with N-Arylacrylamides.

ChemInform ◽  
2014 ◽  
Vol 45 (19) ◽  
pp. no-no
Author(s):  
Weijun Fu ◽  
Fengjuan Xu ◽  
Yuqin Fu ◽  
Mei Zhu ◽  
Jiaqi Yu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Reactions ◽  
Diazonium Salts

Synthesis of stilbene derivatives via visible-light-induced cross-coupling of aryl diazonium salts with nitroalkenes using –NO2 as a leaving group

2016 ◽  
Vol 52 (99) ◽  
pp. 14234-14237 ◽  
Author(s):  
Na Zhang ◽  
Zheng-Jun Quan ◽  
Zhang Zhang ◽  
Yu-Xia Da ◽  
Xi-Cun Wang
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Diazonium Salts ◽  
Leaving Group ◽  
Stilbene Derivatives

Photocatalytic coupling of nitroalkenes with diazonium salts.

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