Efficient Carboxylation of Terminal Alkynes with Carbon Dioxide Catalyzed by Ligand‐Free Copper Catalyst under Ambient Conditions

2019 ◽  
Vol 8 (8) ◽  
pp. 1501-1505 ◽  
Author(s):  
Wan‐Hui Wang ◽  
Lihong Jia ◽  
Xiujuan Feng ◽  
Dingqiao Fang ◽  
Hongyu Guo ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Copper Catalyst ◽  
Terminal Alkynes ◽  
Ambient Conditions ◽  
Ligand Free

A highly active copper catalyst for the hydrogenation of carbon dioxide to formate under ambient conditions

2020 ◽  
Vol 49 (9) ◽  
pp. 2994-3000
Author(s):  
Karan Chaudhary ◽  
Manoj Trivedi ◽  
D. T. Masram ◽  
Abhinav Kumar ◽  
Girijesh Kumar ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Copper Catalyst ◽  
Catalytic Conversion ◽  
Ambient Conditions ◽  
Turnover Number ◽  
Highly Active ◽  
Tin Metal ◽  
Hydrogenation Of Carbon Dioxide

Catalytic conversion of CO2via hydrogenation using in situ gaseous H2 (granulated tin metal and concentrated HCl) to produce the formate salt (HCO2−) with turnover number (TON) values of 326 to 1.065 × 105 in 12 h to 48 h of reaction at 25 °C to 80 °C has been reported.

Silver tungstate: a single-component bifunctional catalyst for carboxylation of terminal alkynes with CO2 in ambient conditions

2015 ◽  
Vol 17 (1) ◽  
pp. 474-479 ◽  
Author(s):  
Chun-Xiang Guo ◽  
Bing Yu ◽  
Jia-Ning Xie ◽  
Liang-Nian He
Keyword(s):  
Room Temperature ◽  
Bifunctional Catalyst ◽  
Single Component ◽  
Terminal Alkynes ◽  
Ambient Conditions ◽  
Ligand Free ◽  
Silver Tungstate

The ligand-free carboxylation of various terminal alkynes promoted by Ag2WO4 was conducted at room temperature and verified with 13CO2.

Ligand-free Cu-catalyzed O-arylation of aliphatic diols

RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 66104-66108 ◽  
Author(s):  
Yufen Zheng ◽  
Wenxing Zou ◽  
Laichun Luo ◽  
Jiabei Chen ◽  
Songwen Lin ◽  
...  
Keyword(s):  
Copper Catalyst ◽  
Scale Up ◽  
Coupling Reaction ◽  
Aryl Iodides ◽  
Ligand Free

Coupling reaction between aryl iodides with aliphatic diols was realized with a ligand-free copper catalyst. This method was successfully applied in the process of scale-up synthesis of medicinal candidate product EMB-3.

scholarly journals Zirconium-Based Metal Organic Frameworks for the Capture of Carbon Dioxide and Ethanol Vapour. A Comparative Study

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7620
Author(s):  
Meryem Saidi ◽  
Phuoc Hoang Ho ◽  
Pankaj Yadav ◽  
Fabrice Salles ◽  
Clarence Charnay ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Van Der Waals Interactions ◽  
Ambient Conditions ◽  
Ethanol Vapour ◽  
Metal Organic ◽  
Experimental Findings ◽  
Two Parameters ◽  
Low Coverage ◽  
Ethanol Adsorption

This paper reports on the comparison of three zirconium-based metal organic frameworks (MOFs) for the capture of carbon dioxide and ethanol vapour at ambient conditions. In terms of efficiency, two parameters were evaluated by experimental and modeling means, namely the nature of the ligands and the size of the cavities. We demonstrated that amongst three Zr-based MOFs, MIP-202 has the highest affinity for CO2 (−50 kJ·mol−1 at low coverage against around −20 kJ·mol−1 for MOF-801 and Muc Zr MOF), which could be related to the presence of amino functions borne by its aspartic acid ligands as well as the presence of extra-framework anions. On the other side, regardless of the ligand size, these three materials were able to adsorb similar amounts of carbon dioxide at 1 atm (between 2 and 2.5 µmol·m−2 at 298 K). These experimental findings were consistent with modeling studies, despite chemisorption effects, which could not be taken into consideration by classical Monte Carlo simulations. Ethanol adsorption confirmed these results, higher enthalpies being found at low coverage for the three materials because of stronger van der Waals interactions. Two distinct sorption processes were proposed in the case of MIP-202 to explain the shape of the enthalpic profiles.

scholarly journals Comparing the Use of High- to Low-Cost Black Carbon and Carbon Dioxide Sensors for Characterizing On-Road Diesel Truck Emissions

Sensors ◽  
2020 ◽  
Vol 20 (23) ◽  
pp. 6714
Author(s):  
Rebecca A. Sugrue ◽  
Chelsea V. Preble ◽  
Thomas W. Kirchstetter
Keyword(s):  
Carbon Dioxide ◽  
Black Carbon ◽  
Emission Factor ◽  
Lower Cost ◽  
Low Cost ◽  
Ambient Air ◽  
Source Characterization ◽  
Ambient Conditions ◽  
Heavy Duty Diesel ◽  
Carbon Dioxide Co2

The exhaust plume capture method is a commonly used approach to measure pollutants emitted by in-use heavy-duty diesel trucks. Lower cost sensors, if used in place of traditional research-grade analyzers, could enable wider application of this method, including use as a monitoring tool to identify high-emitting trucks that may warrant inspection and maintenance. However, low-cost sensors have for the most part only been evaluated under ambient conditions as opposed to source-influenced environments with rapidly changing pollutant concentrations. This study compared black carbon (BC) emission factors determined using different BC and carbon dioxide (CO2) sensors that range in cost from $200 to $20,000. Controlled laboratory experiments show that traditional zero and span steady-state calibration checks are not robust indicators of sensor performance when sampling short duration concentration peaks. Fleet BC emission factor distributions measured at two locations at the Port of Oakland in California with 16 BC/CO2 sensor pairs were similar, but unique sensor pairs identified different high-emitting trucks. At one location, the low-cost PP Systems SBA-5 agreed on the classification of 90% of the high emitters identified by the LI-COR LI-7000 when both were paired with the Magee Scientific AE33. Conversely, lower cost BC sensors when paired with the LI-7000 misclassified more than 50% of high emitters when compared to the AE33/LI-7000. Confidence in emission factor quantification and high-emitter identification improves with larger integrated peak areas of CO2 and especially BC. This work highlights that sensor evaluation should be conducted under application-specific conditions, whether that be for ambient air monitoring or source characterization.

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