Tandem [1,2]-Wittig Rearrangement/Lactonization of γ-Benzyloxy Vinylogous Urethanes: Application to the Synthetic Studies of Maculalactone A, Planchol C and γ-Lycorane

2017 ◽  
Vol 7 (1) ◽  
pp. 145-149 ◽  
Author(s):  
Guo-Ming Ho ◽  
Yu-Jang Li
Author(s):  
Ardalan A. Nabi ◽  
Lydia M. Scott ◽  
Daniel P. Furkert ◽  
Jonathan Sperry

The rare benzoxazepine ring in the alkaloid inducamide C is unstable and prone to rearrangement, indicating that structural revision of the natural product may be necessary.


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