Exceedingly Large Stokes Shift Induced by Low-Barrier H-Bond-Assisted Internal Charge Transfer

Qin Wang; Longfei Xu; Yahui Niu; Mao-Sen Yuan; Yanrong Zhang

doi:10.1002/ajoc.201700179

Exceedingly Large Stokes Shift Induced by Low-Barrier H-Bond-Assisted Internal Charge Transfer

Asian Journal of Organic Chemistry ◽

10.1002/ajoc.201700179 ◽

2017 ◽

Vol 6 (7) ◽

pp. 794-797

Author(s):

Qin Wang ◽

Longfei Xu ◽

Yahui Niu ◽

Mao-Sen Yuan ◽

Yanrong Zhang

Keyword(s):

Charge Transfer ◽

Stokes Shift ◽

Large Stokes Shift ◽

Internal Charge Transfer ◽

Internal Charge

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Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer

Organic Letters ◽

10.1021/ol1019426 ◽

2010 ◽

Vol 12 (21) ◽

pp. 4792-4795 ◽

Cited By ~ 105

Author(s):

Serdar Atilgan ◽

Tugba Ozdemir ◽

Engin U. Akkaya

Keyword(s):

Energy Transfer ◽

Charge Transfer ◽

Excitation Energy ◽

Transfer Process ◽

Stokes Shift ◽

Excitation Energy Transfer ◽

Charge Transfer Process ◽

Internal Charge Transfer ◽

Internal Charge

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A benzothiazole-based fluorescence turn-on sensor for copper(II)

10.21203/rs.3.rs-381861/v1 ◽

2021 ◽

Author(s):

Gyeongjin Kim ◽

Donghwan Choi ◽

Cheal Kim

Keyword(s):

Charge Transfer ◽

Limit Of Detection ◽

Theoretical Calculations ◽

Enhanced Fluorescence ◽

Turn On ◽

Fluorescent Response ◽

Chelation Enhanced Fluorescence ◽

Fluorescence Turn On ◽

Internal Charge Transfer ◽

Internal Charge

Abstract A new benzothiazole-based chemosensor BTN (1-((Z)-(((E)-3-methylbenzo[d]thiazol-2(3H)-ylidene)hydrazono)methyl)naphthalen-2-ol) was synthesized for the detection of Cu2+. BTN could detect Cu2+ with “off-on” fluorescent response from colorless to yellow irrespective of presence of other cations. Limit of detection for Cu2+ was determined to be 3.3 µM. Binding ratio of BTN and Cu2+ turned out to be a 1:1 with the analysis of Job plot and ESI-MS. Sensing feature of Cu2+ by BTN was explained with theoretical calculations, which might be owing to internal charge transfer and chelation-enhanced fluorescence processes.

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Cinnamates. 5. The light-sensitive polycinnamates with internal charge transfer. The study of the local dielectric constant and viscosity

Macromolecules ◽

10.1021/ma00009a005 ◽

1991 ◽

Vol 24 (9) ◽

pp. 2172-2177 ◽

Cited By ~ 6

Author(s):

Jerzy Paczkowski

Keyword(s):

Dielectric Constant ◽

Charge Transfer ◽

Internal Charge Transfer ◽

Internal Charge

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A molecular tailoring approach – a new guide to quantify the energy of push–pull effects: a case study on (E)-3-(1H-pyrrol-2-yl)prop-2-enones

Physical Chemistry Chemical Physics ◽

10.1039/d0cp04432f ◽

2020 ◽

Vol 22 (39) ◽

pp. 22190-22194

Author(s):

Andrei V. Afonin ◽

Danuta Rusinska-Roszak

Keyword(s):

Charge Transfer ◽

New Approach ◽

Internal Charge Transfer ◽

Internal Charge ◽

Molecular Tailoring

We report a new approach to quantify the push–pull effect in molecules with internal charge transfer.

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Internal charge transfer based ratiometric interaction of anionic surfactant with calf thymus DNA bound cationic surfactant: Study I

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy ◽

10.1016/j.saa.2015.07.049 ◽

2016 ◽

Vol 152 ◽

pp. 1-7 ◽

Cited By ~ 4

Author(s):

Abhijit Mukherjee ◽

Tandrima Chaudhuri ◽

Satya Priya Moulik ◽

Manas Banerjee

Keyword(s):

Charge Transfer ◽

Cationic Surfactant ◽

Anionic Surfactant ◽

Calf Thymus Dna ◽

Calf Thymus ◽

Internal Charge Transfer ◽

Internal Charge

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Design and Synthesis of a Highly Sensitive OffâOn Fluorescent Chemosensor for Zinc Ions Utilizing Internal Charge Transfer

Chemistry - A European Journal ◽

10.1002/chem.200901591 ◽

2010 ◽

Vol 16 (2) ◽

pp. 568-572 ◽

Cited By ~ 141

Author(s):

Kenjiro Hanaoka ◽

Yasuaki Muramatsu ◽

Yasuteru Urano ◽

Takuya Terai ◽

Tetsuo Nagano

Keyword(s):

Charge Transfer ◽

Fluorescent Chemosensor ◽

Zinc Ions ◽

Design And Synthesis ◽

Highly Sensitive ◽

Internal Charge Transfer ◽

Internal Charge

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Structural modulation of internal charge transfer in small molecular donors for organic solar cells

Chemical Communications ◽

10.1039/c2cc33921h ◽

2012 ◽

Vol 48 (71) ◽

pp. 8907 ◽

Cited By ~ 70

Author(s):

Antoine Leliège ◽

Charles-Henri Le Régent ◽

Magali Allain ◽

Philippe Blanchard ◽

Jean Roncali

Keyword(s):

Solar Cells ◽

Charge Transfer ◽

Organic Solar Cells ◽

Structural Modulation ◽

Internal Charge Transfer ◽

Internal Charge

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Unusual photoelectric behaviors of Mo-doped TiO2 multilayer thin films prepared by RF magnetron co-sputtering: effect of barrier tunneling on internal charge transfer

Applied Physics A ◽

10.1007/s00339-012-7433-1 ◽

2012 ◽

Vol 110 (1) ◽

pp. 129-135 ◽

Cited By ~ 5

Author(s):

B. X. Yan ◽

S. Y. Luo ◽

X. G. Mao ◽

J. Shen ◽

Q. F. Zhou

Keyword(s):

Thin Films ◽

Charge Transfer ◽

Multilayer Thin Films ◽

Doped Tio2 ◽

Internal Charge Transfer ◽

Internal Charge ◽

Barrier Tunneling

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Luminescence and charge transfer. Part 3. The use of chromophores with ICT (internal charge transfer) excited states in the construction of fluorescent PET (photoinduced electron transfer) pH sensors and related absorption pH sensors with aminoalkyl side chains

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29930001611 ◽

1993 ◽

pp. 1611 ◽

Cited By ~ 57

Author(s):

A. Prasanna de Silva ◽

H. Q. Nimal Gunaratne ◽

P. L. Mark Lynch ◽

Alan J. Patty ◽

Graham L. Spence

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Excited States ◽

Photoinduced Electron Transfer ◽

Side Chains ◽

Ph Sensors ◽

Internal Charge Transfer ◽

Internal Charge

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Twisted internal charge transfer emission in B,B-bis(mesityl) pyrroloboranes

Journal of Physical Organic Chemistry ◽

10.1002/poc.610020109 ◽

1989 ◽

Vol 2 (1) ◽

pp. 89-92 ◽

Cited By ~ 2

Author(s):

David R. Brittelli ◽

David F. Eaton

Keyword(s):

Charge Transfer ◽

Internal Charge Transfer ◽

Internal Charge

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Exceedingly Large Stokes Shift Induced by Low-Barrier H-Bond-Assisted Internal Charge Transfer

Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer

A benzothiazole-based fluorescence turn-on sensor for copper(II)

Cinnamates. 5. The light-sensitive polycinnamates with internal charge transfer. The study of the local dielectric constant and viscosity

A molecular tailoring approach – a new guide to quantify the energy of push–pull effects: a case study on (E)-3-(1H-pyrrol-2-yl)prop-2-enones

Internal charge transfer based ratiometric interaction of anionic surfactant with calf thymus DNA bound cationic surfactant: Study I

Design and Synthesis of a Highly Sensitive OffâOn Fluorescent Chemosensor for Zinc Ions Utilizing Internal Charge Transfer

Structural modulation of internal charge transfer in small molecular donors for organic solar cells

Unusual photoelectric behaviors of Mo-doped TiO2 multilayer thin films prepared by RF magnetron co-sputtering: effect of barrier tunneling on internal charge transfer

Luminescence and charge transfer. Part 3. The use of chromophores with ICT (internal charge transfer) excited states in the construction of fluorescent PET (photoinduced electron transfer) pH sensors and related absorption pH sensors with aminoalkyl side chains

Twisted internal charge transfer emission in B,B-bis(mesityl) pyrroloboranes

Design and Synthesis of a Highly Sensitive OffâOn Fluorescent Chemosensor for Zinc Ions Utilizing Internal Charge Transfer