Heat and mass transport in microwave drying of porous materials in a spouted bed

AIChE Journal ◽  
2001 ◽  
Vol 47 (7) ◽  
pp. 1499-1512 ◽  
Author(s):  
H. Feng ◽  
J. Tang ◽  
R. P. Cavalieri ◽  
O. A. Plumb
Keyword(s):  
Mass Transport ◽  
Porous Materials ◽  
Microwave Drying ◽  
Spouted Bed ◽  
Heat And Mass Transport

scholarly journals The Impact of Microstructure Geometry on the Mass Transport in Artificial Pores: A Numerical Approach

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Matthias Galinsky ◽  
Ulf Sénéchal ◽  
Cornelia Breitkopf
Keyword(s):  
Mass Transport ◽  
Porous Materials ◽  
Effective Diffusion ◽  
Direct Simulation Monte Carlo ◽  
Numerical Approach ◽  
Porous System ◽  
Length Scales ◽  
General Evaluation ◽  
Pulse Experiment ◽  
The Impact

The microstructure of porous materials used in heterogeneous catalysis determines the mass transport inside networks, which may vary over many length scales. The theoretical prediction of mass transport phenomena in porous materials, however, is incomplete and is still not completely understood. Therefore, experimental data for every specific porous system is needed. One possible experimental technique for characterizing the mass transport in such pore networks is pulse experiments. The general evaluation of experimental outcomes of these techniques follows the solution of Fick’s second law where an integral and effective diffusion coefficient is recognized. However, a detailed local understanding of diffusion and sorption processes remains a challenge. As there is lack of proved models covering different length scales, existing classical concepts need to be evaluated with respect to their ability to reflect local geometries on the nanometer level. In this study, DSMC (Direct Simulation Monte Carlo) models were used to investigate the impact of pore microstructures on the diffusion behaviour of gases. It can be understood as a virtual pulse experiment within a single pore or a combination of different pore geometries.

Measurement and Modeling of Latent Heat Release During Freezing of Aqueous Solutions in a Small Container

2000 ◽  
Author(s):  
Ramachandra V. Devireddy ◽  
John C. Bischof ◽  
Perry H. Leo ◽  
John S. Lowengrub
Keyword(s):  
Mass Transport ◽  
Heat Release ◽  
Latent Heat ◽  
Pure Water ◽  
Heat Of Fusion ◽  
Freezing Process ◽  
Latent Heat Release ◽  
Aqueous Systems ◽  
Heat And Mass Transport ◽  
Latent Heat Of Fusion

Abstract The latent heat of fusion, ΔHf of a cryobiological medium (a solute laden aqueous solution) is a crucial parameter in the cryopreservation process. The latent heat has often been approximated by that of pure water (∼ 335 mJ/mg). However, recent calorimetric (DSC - Pyris 1) measurements suggest that the actual magnitude of latent heat of fusion during freezing of solute laden aqueous systems is far less. Fourteen different pre-nucleated solute laden aqueous systems (NaCl-H2O, Phosphate Buffered Saline or PBS, serum free RPMI, cell culture medium, glycerol and Anti Freeze Protein solutions) were found to have significantly lower ΔHf than that of pure water (Devireddy and Bischof, 1998). In the present study additional calorimetric experiments are performed at 1, 5 and 20 °C/min in five representative cryobiological media (isotonic or 1× NaCl-H2O, 10× NaCl-H2O, 1× PBS, 5× PBS and 10× PBS) to determine the kinetics of ice crystallization. The temperature (T) and time (t) dependence of the latent heat release is measured. The experimental data shows that at a fixed temperature, the fraction of heat released at higher cooling rates (5 and 20 °C/min) is lower than at 1 °C/min for all the solutions studied. We then sought a simple model that could predict the experimentally measured behavior and examined the full set of heat and mass transport equations during the freezing process in a DSC sample pan. The model neglects the interaction between the growing ice crystals and is most appropriate during the early stages of the freezing process. An examination of the coefficients in the heat and mass transport equations shows that heat transport occurs much more rapidly than solute transport. Hence, the full model reduces to one in which the temperature profile is constant in space while the solute concentration profile obeys the full time and space dependent diffusion equation. The model reveals the important physical parameters controlling the mass transport at the freezing interface and further elucidates the experimental results, i.e. the temperature and time dependence of the latent heat release.

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